Determining 3D Molecular Conformations with Ultrafast Multiple- Dimensional Vibrational Spectroscopy

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	Determining 3D Molecular Conformations with Ultrafast Multiple- Dimensional Vibrational Spectroscopy
	Chen Hai-Long 2,3; Bian Hong-Tao 4; Zheng Jun-Rong 1
刊名	ACTA PHYSICO-CHIMICA SINICA
	2017-01-15
卷号	33 期号:1 页码:40-62
关键词	Multiple-dimensional Vibrational Spectroscopy Ultrafast Spectroscopy 2d Infrared Spectroscopy Molecular Conformation Vibrational Energy Transfer
英文摘要	In recent years, ultrafast multiple-dimensional vibrational spectroscopy has been widely applied to studies of molecular structures and ultrafast dynamics in various condensed phases, and is expected to become a new generation of routine analytical tool for determining microstructures and ultrafast behaviors in molecular systems. In this review, we introduce in detail a method of determining three-dimensional (3D) molecular conformations with ultrafast multiple-dimensional vibrational spectroscopy. The introduction of our research follows two directions: (1) obtaining relative spatial orientations of different groups in a molecular system and finally determining molecular conformations by measuring cross angles of vibrational transition dipole moments; and (2) exploring the nature of vibrational energy transfers and determining molecular distances with experimentally measured vibrational energy transfer rates.
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/38029]
专题	化学研究所_其它
作者单位	1.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China 2.Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Inst Phys, Key Lab Soft Matter Phys, Beijing 100190, Peoples R China 4.Shaanxi Normal Univ, Sch Chem & Chem Engn, Xian 710119, Peoples R China
推荐引用方式 GB/T 7714	Chen Hai-Long,Bian Hong-Tao,Zheng Jun-Rong. Determining 3D Molecular Conformations with Ultrafast Multiple- Dimensional Vibrational Spectroscopy[J]. ACTA PHYSICO-CHIMICA SINICA,2017,33(1):40-62.
APA	Chen Hai-Long,Bian Hong-Tao,&Zheng Jun-Rong.(2017).Determining 3D Molecular Conformations with Ultrafast Multiple- Dimensional Vibrational Spectroscopy.ACTA PHYSICO-CHIMICA SINICA,33(1),40-62.
MLA	Chen Hai-Long,et al."Determining 3D Molecular Conformations with Ultrafast Multiple- Dimensional Vibrational Spectroscopy".ACTA PHYSICO-CHIMICA SINICA 33.1(2017):40-62.