Metal-mediated catalysis in the gas phase: A review

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	Metal-mediated catalysis in the gas phase: A review
	Li, Xiao-Na 1; Zou, Xiu-Ping 1,2; He, Sheng-Gui 1
刊名	CHINESE JOURNAL OF CATALYSIS
	2017-09-01
卷号	38 期号:9 页码:1515-1527
关键词	Metal Catalysis Clusters Single Atom Catalysts Carbon Monoxide Methane
英文摘要	This review summarizes a variety of experimentally identified gas-phase catalytic cycles, all of which are mediated by atomic metal ions, bare metal clusters, metal oxide clusters or metal complexes. Emphasis is placed on the latest advances in the unique catalytic reactivity of cluster-confined single noble metal atoms. The cycles discussed in this paper cover a wide range of inorganic and organic molecules. The use of start-of-the-art mass spectrometric instrumentation in conjunction with quantum chemistry calculations is also reported, as these techniques have determined the mechanistic details of the elementary steps of such catalytic cycles. The important role of gas-phase data in guiding the rational design of better-performing catalysts in related condensed phase reactions is also examined. In particular, this review focuses on the following three topics: (1) the catalytic oxidation of carbon monoxide, (2) the catalytic functionalization of methane, and (3) catalytic decarboxylation. (C) 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences.
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/41107]
专题	化学研究所_分子动态与稳态结构实验室
作者单位	1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China 2.South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510641, Guangdong, Peoples R China
推荐引用方式 GB/T 7714	Li, Xiao-Na,Zou, Xiu-Ping,He, Sheng-Gui. Metal-mediated catalysis in the gas phase: A review[J]. CHINESE JOURNAL OF CATALYSIS,2017,38(9):1515-1527.
APA	Li, Xiao-Na,Zou, Xiu-Ping,&He, Sheng-Gui.(2017).Metal-mediated catalysis in the gas phase: A review.CHINESE JOURNAL OF CATALYSIS,38(9),1515-1527.
MLA	Li, Xiao-Na,et al."Metal-mediated catalysis in the gas phase: A review".CHINESE JOURNAL OF CATALYSIS 38.9(2017):1515-1527.