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Superconductivity in a Copper(II)-Based Coordination Polymer with Perfect Kagome Structure
Huang, Xing1,3; Zhang, Shuai2; Liu, Liyao1,3; Yu, Lei4; Chen, Genfu2,3,5; Xu, Wei1,3; Zhu, Daoben1,3
刊名ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
2018-01-02
卷号57期号:1页码:146-150
关键词Coordination Polymers Kagome Lattice Quantum Criticality Quantum Spin Liquids Superconductivity
英文摘要A highly crystalline copper(II) benzenehexathiolate coordination polymer (Cu-BHT) has been prepared. The two-dimensional kagome structure has been confirmed by powder X-ray diffraction, high-resolution transmission electron microscopy, and high-resolution scanning transmission electron microscopy. The as-prepared sample exhibits bulk superconductivity at about 0.25K, which is confirmed by the zero resistivity, AC magnetic susceptibility, and specific heat measurements. Another diamagnetic transition at about 3K suggests that there is a second superconducting phase that may be associated with a single layer or few layers of Cu-BHT. It is the first time that superconductivity has been observed in a coordination polymer.
语种英语
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/38473]  
专题化学研究所_有机固体实验室
作者单位1.Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, POB 603, Beijing 100190, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Univ Kentucky, Dept Chem, Lexington, KY 40506 USA
5.Collaborat Innovat Ctr Quantum Matter, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Huang, Xing,Zhang, Shuai,Liu, Liyao,et al. Superconductivity in a Copper(II)-Based Coordination Polymer with Perfect Kagome Structure[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(1):146-150.
APA Huang, Xing.,Zhang, Shuai.,Liu, Liyao.,Yu, Lei.,Chen, Genfu.,...&Zhu, Daoben.(2018).Superconductivity in a Copper(II)-Based Coordination Polymer with Perfect Kagome Structure.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(1),146-150.
MLA Huang, Xing,et al."Superconductivity in a Copper(II)-Based Coordination Polymer with Perfect Kagome Structure".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.1(2018):146-150.
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