Natural and Artificial Mn4Ca Cluster for the Water Splitting Reaction

	Natural and Artificial Mn4Ca Cluster for the Water Splitting Reaction
	Chen, Changhui 1,2; Li, Yanxi 1,2; Zhao, Guoqing 1,2; Yao, Ruoqing 1; Zhang, Chunxi 1
刊名	CHEMSUSCHEM
	2017-11-23
卷号	10 期号:22 页码:4403-4408
关键词	Artificial Photosynthesis Calcium Manganese Photosystem Ii Water Splitting
英文摘要	The oxygen-evolving center (OEC) in photosystem II (PSII) is a unique biological catalyst that splits water into electrons, protons, and O-2 by using solar energy. Recent crystallographic studies have revealed that the structure of the OEC is an asymmetric Mn4Ca cluster, which provides a blueprint to develop man-made water-splitting catalysts for artificial photosynthesis. Although it is a great challenge to mimic the whole structure and function of the OEC in the laboratory, significant advances have recently been achieved. In this Minireview, recent progress on mimicking the natural OEC is discussed. New strategies are suggested to construct more stable and efficient new generation of catalytic materials for the water splitting reaction based on the artificial Mn4Ca cluster in the future.
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/38316]
专题	化学研究所_光化学实验室
作者单位	1.Chinese Acad Sci, Inst Chem, Lab Photochem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Chen, Changhui,Li, Yanxi,Zhao, Guoqing,et al. Natural and Artificial Mn4Ca Cluster for the Water Splitting Reaction[J]. CHEMSUSCHEM,2017,10(22):4403-4408.
APA	Chen, Changhui,Li, Yanxi,Zhao, Guoqing,Yao, Ruoqing,&Zhang, Chunxi.(2017).Natural and Artificial Mn4Ca Cluster for the Water Splitting Reaction.CHEMSUSCHEM,10(22),4403-4408.
MLA	Chen, Changhui,et al."Natural and Artificial Mn4Ca Cluster for the Water Splitting Reaction".CHEMSUSCHEM 10.22(2017):4403-4408.