Multiresponsive Vesicles Composed of Amphiphilic Azacalix[4]pyridine Derivatives
Fa, Shi-Xin1; Wang, Xu-Dong1,3; Wang, Qi-Qiang1,3; Ao, Yu-Fei1; Wang, De-Xian1,3; Wang, Mei-Xiang2
刊名ACS APPLIED MATERIALS & INTERFACES
2017-03-29
卷号9期号:12页码:10378-10382
关键词Vesicle Heteracalixaromatics Azacalix[4]Pyridine Amphiphile Multiresponsive
英文摘要Biomimicry of multiresponsive recognition of cell membrane with artificial membranes is challengeable. In this work, we designed azacalix[4]pyridine-based amphiphilic molecules 1 and 2. The self-assembly behaviors of 1 and 2 were investigated in aqueous medium. As demonstrated by DLS, SEM, TEM, and LSCM measurements, 1 formed stable vesicles (size 322 nm) in a mixture of THF/water, whereas 2 produced giant vesicles with decreased stability (size 928 nm). The vesicles composed of 1, with surface being engineered with the cavities of azacalix[4]pyridines, showed selective responses to a variety of guests including zinc ion, hydroquinone, and proton as monitored by DLS.
语种英语
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/38288]  
专题化学研究所_分子识别与功能实验室
作者单位1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Tsinghua Univ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Minist Educ, Beijing 100084, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Fa, Shi-Xin,Wang, Xu-Dong,Wang, Qi-Qiang,et al. Multiresponsive Vesicles Composed of Amphiphilic Azacalix[4]pyridine Derivatives[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9(12):10378-10382.
APA Fa, Shi-Xin,Wang, Xu-Dong,Wang, Qi-Qiang,Ao, Yu-Fei,Wang, De-Xian,&Wang, Mei-Xiang.(2017).Multiresponsive Vesicles Composed of Amphiphilic Azacalix[4]pyridine Derivatives.ACS APPLIED MATERIALS & INTERFACES,9(12),10378-10382.
MLA Fa, Shi-Xin,et al."Multiresponsive Vesicles Composed of Amphiphilic Azacalix[4]pyridine Derivatives".ACS APPLIED MATERIALS & INTERFACES 9.12(2017):10378-10382.
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