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A Synergetic Effect of Molecular Weight and Fluorine in All-Polymer Solar Cells with Enhanced Performance
Chen, Shanshan1; An, Yujin1; Dutta, Gitish K.2; Kim, Yiho1; Zhang, Zhi-Guo3; Li, Yongfang3; Yang, Changduk1
刊名ADVANCED FUNCTIONAL MATERIALS
2017
卷号27期号:2
英文摘要A synergetic effect of molecular weight (M-n) and fluorine (F) on the performance of all-polymer solar cells (all-PSCs) is comprehensively investigated by tuning the M-n of the acceptor polymer poly((N, N'-bis(2-octyldodecyl)-naphthalene- 1,4,5,8-bis(dicarboximide)-2,6-diyl)-alt-5,5'-(2,2'-bithiophene)) (P(NDI2OD-T2)) and the F content of donor polymer poly(2,3-bis-(3-octyloxyphenyl) quinoxaline-5,8-dyl-alt-thiophene-2,5-diyl). Both M-n and F variations strongly influence the charge transport properties and morphology of the blend films, which have a significant impact on the photovoltaic performance of all-PSCs. In particular, the effectiveness of high M-n in increasing power conversion efficiency (PCE) can be greatly improved by the devices based on optimum F content, reaching a PCE of 7.31% from the best all-PSC combination. These findings enable us to further understand the working principles of all-PSCs with a view on achieving even higher power conversion efficiency in the future.
语种英语
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/38034]  
专题化学研究所_有机固体实验室
作者单位1.Ulsan Natl Inst Sci & Technol, Low Dimens Carbon Mat Ctr, Sch Energy & Chem Engn, Dept Energy Engn, 50 UNIST Gil, Ulsan 44919, South Korea
2.Natl Inst Technol Meghalaya, Dept Chem, Shillong, Meghalaya, India
3.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Chen, Shanshan,An, Yujin,Dutta, Gitish K.,et al. A Synergetic Effect of Molecular Weight and Fluorine in All-Polymer Solar Cells with Enhanced Performance[J]. ADVANCED FUNCTIONAL MATERIALS,2017,27(2).
APA Chen, Shanshan.,An, Yujin.,Dutta, Gitish K..,Kim, Yiho.,Zhang, Zhi-Guo.,...&Yang, Changduk.(2017).A Synergetic Effect of Molecular Weight and Fluorine in All-Polymer Solar Cells with Enhanced Performance.ADVANCED FUNCTIONAL MATERIALS,27(2).
MLA Chen, Shanshan,et al."A Synergetic Effect of Molecular Weight and Fluorine in All-Polymer Solar Cells with Enhanced Performance".ADVANCED FUNCTIONAL MATERIALS 27.2(2017).
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