Intriguing Structural Transition Inducing Variable Birefringences in ABa(2)MS(4)Cl (A = Rb, Cs; M = Ge, Sn)

doi:10.1021/acs.inorgchem.8b01788

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 中国科学院特殊环境功能材料与器件重点试验室

	Intriguing Structural Transition Inducing Variable Birefringences in ABa(2)MS(4)Cl (A = Rb, Cs; M = Ge, Sn)
	Chu, Y (Chu, Yu)[ 1,2,3 ]; Wu, K (Wu, Kui)[ 1,2 ]; Su, X (Su, Xin)[ 1,2 ]; Han, J (Han, Jian)[ 1,2 ]; Yang, ZH (Yang, Zhihua)[ 1,2 ]; Pan, SL (Pan, Shilie)[ 1,2 ]
刊名	INORGANIC CHEMISTRY
	2018
卷号	57 期号:18 页码:11310-11313
ISSN号	0020-1669
DOI	10.1021/acs.inorgchem.8b01788
英文摘要	A suite of quinary thiohalides, ABa(2)MS(4)Cl (A = Rb, Cs; M = Ge, Sn), have been successfully synthesized. ABa(2)MS(4)Cl (A = Rb, Cs; M = Ge, Sn) undergoes an interesting structural transition from P2(1)/c (alpha phase) to I4/mcm (beta phase), which also leads to obvious disparities on the birefringence from 0.041 (alpha phase) to 0.094 (beta phase). Moreover, the result of deploying a real-space atom-cutting method on ABa(2)MS(4)Cl reveals that their (MS4)(4-) groups may take the major effect in terms of the anisotropy by a structural transition.
WOS记录号	WOS:000445165400003
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/5593]
专题	新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室新疆理化技术研究所_材料物理与化学研究室
通讯作者	Pan, SL (Pan, Shilie)[ 1,2 ]
作者单位	1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Chu, Y ,Wu, K ,Su, X ,et al. Intriguing Structural Transition Inducing Variable Birefringences in ABa(2)MS(4)Cl (A = Rb, Cs; M = Ge, Sn)[J]. INORGANIC CHEMISTRY,2018,57(18):11310-11313.
APA	Chu, Y ,Wu, K ,Su, X ,Han, J ,Yang, ZH ,&Pan, SL .(2018).Intriguing Structural Transition Inducing Variable Birefringences in ABa(2)MS(4)Cl (A = Rb, Cs; M = Ge, Sn).INORGANIC CHEMISTRY,57(18),11310-11313.
MLA	Chu, Y ,et al."Intriguing Structural Transition Inducing Variable Birefringences in ABa(2)MS(4)Cl (A = Rb, Cs; M = Ge, Sn)".INORGANIC CHEMISTRY 57.18(2018):11310-11313.