Daphenylline, a New Alkaloid with an Unusual Skeleton, from Daphniphyllum longeracemosum | |
Zhang, Qiang1,2; Di, Ying-Tong1; Li, Chun-Shun1; Fang, Xin1; Tan, Cheng-Jian1; Zhang, Zhen1; Zhang, Yu1; He, Hong-Ping1; Li, Shun-Lin1; Hao, Xiao-Jiang1 | |
刊名 | ORGANIC LETTERS |
2009-06-04 | |
卷号 | 11期号:11页码:2357-2359 |
关键词 | Density-functional Theory Optical-rotation Unprecedented Skeletons Ring-system Calycinum Construction Calycillum Macropodum Paxianum Cascade |
ISSN号 | 1523-7060 |
DOI | 10.1021/ol9007958 |
文献子类 | Article |
英文摘要 | A new alkaloid, daphenylline (1), with an unprecedented rearranged 22-nor-calyciphylline skeleton, was isolated from the fruits of Daphniphyllum longeracemosum. Its structure and stereochemistry were elucidated on the basis of spectroscopic and computational approaches. A plausible biosynthetic pathway of 1 was also proposed. |
学科主题 | Chemistry, Organic |
WOS关键词 | DENSITY-FUNCTIONAL THEORY ; OPTICAL-ROTATION ; UNPRECEDENTED SKELETONS ; RING-SYSTEM ; CALYCINUM ; CONSTRUCTION ; CALYCILLUM ; MACROPODUM ; PAXIANUM ; CASCADE |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000266546300034 |
资助机构 | Ministry of Science and Technology [2009CB522303]; National Science Foundation [1130830114, 3930830114]; West Doctor Foundation of Chinese Academy of Sciences [2908065112w1] |
公开日期 | 2012-03-21 |
内容类型 | 期刊论文 |
源URL | [http://ir.kib.ac.cn:8080/handle/151853/4268] |
专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, State Key Lab Phytochem & Plant Resources W China, Kunming Inst Bot, Kunming 650204, Yunnan, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Qiang,Di, Ying-Tong,Li, Chun-Shun,et al. Daphenylline, a New Alkaloid with an Unusual Skeleton, from Daphniphyllum longeracemosum[J]. ORGANIC LETTERS,2009,11(11):2357-2359. |
APA | Zhang, Qiang.,Di, Ying-Tong.,Li, Chun-Shun.,Fang, Xin.,Tan, Cheng-Jian.,...&Hao, Xiao-Jiang.(2009).Daphenylline, a New Alkaloid with an Unusual Skeleton, from Daphniphyllum longeracemosum.ORGANIC LETTERS,11(11),2357-2359. |
MLA | Zhang, Qiang,et al."Daphenylline, a New Alkaloid with an Unusual Skeleton, from Daphniphyllum longeracemosum".ORGANIC LETTERS 11.11(2009):2357-2359. |
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