Hydrogen-bonding system in amarillite, NaFe(SO4)(2)(H2O)(6): the structure refinement

doi:10.1127/ejm/2016/0028-2567

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	Hydrogen-bonding system in amarillite, NaFe(SO4)(2)(H2O)(6): the structure refinement
	Yang, Zhuming 1; Giester, Gerald 2
刊名	EUROPEAN JOURNAL OF MINERALOGY
	2016-12-31
卷号	28 期号:5 页码:953-958
关键词	Amarillite Hydrogen Bonding Hydrated Sulfate Crystal Structure Infrared Oxidation Zone Of Pb-zn Deposit
ISSN号	0935-1221
DOI	10.1127/ejm/2016/0028-2567
文献子类	Article
英文摘要	The crystal structure of amarillite, NaFe(SO4)(2)(H2O)(6), was redetermined from a single crystal from Xitieshan, Qinghai Province, China. In complement to previous work, all non-H atoms were refined with anisotropic displacement parameters and H-atoms were located by difference Fourier methods and refined from X-ray diffraction data. The structure can be formally described by octahedral-tetrahedral "sheets" of corner-sharing [NaO4(H2O)(2)] octahedra and (SO4) tetrahedra, which constitute a structural sheet with composition [Na(SO4)(2)(H2O)(2)](3-)extending parallel to (001). The resultant sheets are held together by interstitial Fe3+ cations and hydrogen bonds. The [NaO4(H2O)(2)] octahedra donate four hydrogen bonds to the oxygen atoms of neighboring (SO4) tetrahedra, thus strengthening connections in three dimensions. The interstitial [FeO2(H2O)(4)] octahedra are linked by eight hydrogen bonds to the vertices of the adjacent octahedral-tetrahedral sheets, further stabilizing the crystal structure of amarillite. The FTIR spectrum of amarillite shows a strong absorption between 3000 cm(-1) and 3500 cm(-1) with maxima at similar to 3110 m(-1) and similar to 3442 cm(-1), which is in accordance with the O-H center dot center dot center dot O distances derived from structure data.
WOS关键词	CRYSTAL-STRUCTURE ; SULFATE ; SIDERONATRITE ; MINERALS ; VALENCE
WOS研究方向	Mineralogy
语种	英语
出版者	E SCHWEIZERBARTSCHE VERLAGSBUCHHANDLUNG
WOS记录号	WOS:000399807600008
资助机构	National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063) ; National Natural Science Foundation of China(41272063)
内容类型	期刊论文
源URL	[http://ir.iggcas.ac.cn/handle/132A11/52961]
专题	地质与地球物理研究所_岩石圈演化研究室
通讯作者	Giester, Gerald
作者单位	1.Chinese Acad Sci, Inst Geol & Geophys, Beijing 100029, Peoples R China 2.Univ Vienna, Inst Mineral & Kristallog, A-1090 Vienna, Austria
推荐引用方式 GB/T 7714	Yang, Zhuming,Giester, Gerald. Hydrogen-bonding system in amarillite, NaFe(SO4)(2)(H2O)(6): the structure refinement[J]. EUROPEAN JOURNAL OF MINERALOGY,2016,28(5):953-958.
APA	Yang, Zhuming,&Giester, Gerald.(2016).Hydrogen-bonding system in amarillite, NaFe(SO4)(2)(H2O)(6): the structure refinement.EUROPEAN JOURNAL OF MINERALOGY,28(5),953-958.
MLA	Yang, Zhuming,et al."Hydrogen-bonding system in amarillite, NaFe(SO4)(2)(H2O)(6): the structure refinement".EUROPEAN JOURNAL OF MINERALOGY 28.5(2016):953-958.