High Anisotropy in Tubular Layered Exfoliated KP15 | |
Tian, Nan1,2; Yang, Yanhan1,3; Liu, Danmin1,2; Liu, Xuelu4; Tan, Ping-Heng4; Zhang, Dong4; Chang, Kai4; Li, Hui1,2; Zhao, Minjian5; Li, Jian Rong5 | |
刊名 | ACS NANO |
2018-02-01 | |
卷号 | 12期号:2页码:1712-1719 |
关键词 | KP15 layered-like structure anisotropy anisotropic Raman response anisotropic exciton emission anisotropic excitation |
ISSN号 | 1936-0851 |
DOI | 10.1021/acsnano.7b08368 |
文献子类 | Article |
英文摘要 | Two-dimensional (2D) materials with high anisotropic properties, such as black phosphorus and ReS2, show amazing potential for applications in future nano electronic and optoelectronic devices. However, degradation of black phosphorus under ambient conditions and the expensiveness of Re block their application. In this study, another layered material, KP15, that has highly anisotropic properties was successfully prepared. The detailed crystal structure and electron-density distribution calculation reveal that KP15 exhibits an anisotropic layered structure with two rows of P tubes connected by K atoms that are antiparallel in a single layer. Outstanding chemical stability, angular dependence of the Raman response, excitation, and exciton emission at room temperature have been found in exfoliated KP15 nanoribbons. Importantly, the exciton emission at room temperature suggests the existence of a large exciton binding energy. Our results indicate that, because this layered material, KP15, has high anisotropic properties and ultrachemical stability and is derived from abundant raw materials, it has great potential for applications in optoelectronic devices. |
WOS关键词 | GENERALIZED GRADIENT APPROXIMATION ; INDIUM-PHOSPHIDE NANOWIRES ; MAXIMUM-ENTROPY METHOD ; MONOLAYER WSE2 ; GRAPHENE ; PHOTOLUMINESCENCE ; OPTOELECTRONICS ; POLYPHOSPHIDES ; ELECTRONICS ; ACCURATE |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000426615600082 |
资助机构 | Science and Technology Commission of Beijing Municipality(Z151100003315018) ; Science and Technology Commission of Beijing Municipality(Z151100003315018) ; National Natural Science Foundation of China(61575010 ; National Natural Science Foundation of China(61575010 ; Natural Science Foundation of Beijing(4162016) ; Natural Science Foundation of Beijing(4162016) ; NSFC 51671006) ; NSFC 51671006) ; Science and Technology Commission of Beijing Municipality(Z151100003315018) ; Science and Technology Commission of Beijing Municipality(Z151100003315018) ; National Natural Science Foundation of China(61575010 ; National Natural Science Foundation of China(61575010 ; Natural Science Foundation of Beijing(4162016) ; Natural Science Foundation of Beijing(4162016) ; NSFC 51671006) ; NSFC 51671006) ; Science and Technology Commission of Beijing Municipality(Z151100003315018) ; Science and Technology Commission of Beijing Municipality(Z151100003315018) ; National Natural Science Foundation of China(61575010 ; National Natural Science Foundation of China(61575010 ; Natural Science Foundation of Beijing(4162016) ; Natural Science Foundation of Beijing(4162016) ; NSFC 51671006) ; NSFC 51671006) ; Science and Technology Commission of Beijing Municipality(Z151100003315018) ; Science and Technology Commission of Beijing Municipality(Z151100003315018) ; National Natural Science Foundation of China(61575010 ; National Natural Science Foundation of China(61575010 ; Natural Science Foundation of Beijing(4162016) ; Natural Science Foundation of Beijing(4162016) ; NSFC 51671006) ; NSFC 51671006) |
内容类型 | 期刊论文 |
源URL | [http://ir.iggcas.ac.cn/handle/132A11/83064] |
专题 | 中国科学院地质与地球物理研究所 |
通讯作者 | Liu, Danmin; Zhang, Yongzhe |
作者单位 | 1.Beijing Univ Technol, Beijing Key Lab Microstruct & Properties Adv Mat, 100 Pingleyuan, Beijing 100124, Peoples R China 2.Beijing Univ Technol, Inst Microstruct & Property Adv Mat, 100 Pingleyuan, Beijing 100124, Peoples R China 3.Beijing Univ Technol, Coll Mat Sci & Engn, 100 Pingleyuan, Beijing 100124, Peoples R China 4.Chinese Acad Sci, Inst Semicond, State Key Lab Superlattices & Microstruct, 35 Qinghua East Rd, Beijing 100083, Peoples R China 5.Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Beijing Key Lab Green Catalysis & Separat, 100 Pingleyuan, Beijing 100124, Peoples R China 6.Chinese Acad Sci, Inst Geol & Geophys, Electron Microscopy Lab, IGGCAS, 19 Beitucheng West Rd, Beijing 100029, Peoples R China |
推荐引用方式 GB/T 7714 | Tian, Nan,Yang, Yanhan,Liu, Danmin,et al. High Anisotropy in Tubular Layered Exfoliated KP15[J]. ACS NANO,2018,12(2):1712-1719. |
APA | Tian, Nan.,Yang, Yanhan.,Liu, Danmin.,Liu, Xuelu.,Tan, Ping-Heng.,...&Zhang, Yongzhe.(2018).High Anisotropy in Tubular Layered Exfoliated KP15.ACS NANO,12(2),1712-1719. |
MLA | Tian, Nan,et al."High Anisotropy in Tubular Layered Exfoliated KP15".ACS NANO 12.2(2018):1712-1719. |
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