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	The fcc structure isomerization in gold nanoclusters
	Zhuang, Shengli1,2; Liao, Lingwen1; Li, Man-Bo1; Yao, Chuanhao1; Zhao, Yan1,2; Dong, Hongwei1,2; Li, Jin3; Deng, Haiteng4; Li, Lingling5; Wu, Zhikun1
刊名	NANOSCALE
	2017-10-21
卷号	9期号:39页码:14809-14813
DOI	10.1039/c7nr05239a
文献子类	Article
英文摘要	Structural isomerization is an important concept in organic chemistry and it is recently found to be applicable to thiolated gold nanoparticles. However, to the best of our knowledge, the isomerization with the kernel structure of the cluster changed while maintaining fcc packing was not previously found. Here, we report such a structural isomerization by synthesizing a novel gold nanocluster and solving its atomic structure. The as-obtained novel gold nanocluster Au-52(PET)(32) (PET = phenylethanethiolate) has completely the same Au/S molar ratio as a well-known gold nanocluster Au-52(TBBT)(32) (TBBT = 4-tert-butyl-benzenethiolate) but an essentially different fcc structure. As a result of fcc structure isomerization, Au-52(PET)(32) has remarkably different UV/vis/NIR absorption from Au-52(TBBT)(32). Another interesting finding in this work is that the kernel of Au-52(PET)(32) has high-indexed (311)-like facets, which is not previously reported in the structures of gold nanoclusters to the best of our knowledge.
WOS关键词	X-RAY CRYSTALLOGRAPHY ; PROTECTED AU-25 CLUSTER ; OPTICAL-PROPERTIES ; THEORETICAL-ANALYSIS ; METAL NANOCLUSTERS ; CRYSTAL-STRUCTURE ; NANOPARTICLE ; NANOCRYSTALS ; MONOLAYER ; COMPLEXES
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
语种	英语
WOS记录号	WOS:000412940000007
资助机构	National Natural Science Foundation of China(21222301 ; National Natural Science Foundation of China(21222301 ; National Natural Science Foundation of China(21222301 ; National Natural Science Foundation of China(21222301 ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; Anhui Provincial Natural Science Foundation(1608085QB31) ; Anhui Provincial Natural Science Foundation(1608085QB31) ; Anhui Provincial Natural Science Foundation(1608085QB31) ; Anhui Provincial Natural Science Foundation(1608085QB31) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; 21528303 ; 21528303 ; 21528303 ; 21528303 ; 21603234 ; 21603234 ; 21603234 ; 21603234 ; 21771186 ; 21771186 ; 21771186 ; 21771186 ; 21171170 ; 21171170 ; 21171170 ; 21171170 ; 21501182 ; 21501182 ; 21501182 ; 21501182 ; 21601193) ; 21601193) ; 21601193) ; 21601193) ; National Natural Science Foundation of China(21222301 ; National Natural Science Foundation of China(21222301 ; National Natural Science Foundation of China(21222301 ; National Natural Science Foundation of China(21222301 ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; Anhui Provincial Natural Science Foundation(1608085QB31) ; Anhui Provincial Natural Science Foundation(1608085QB31) ; Anhui Provincial Natural Science Foundation(1608085QB31) ; Anhui Provincial Natural Science Foundation(1608085QB31) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; 21528303 ; 21528303 ; 21528303 ; 21528303 ; 21603234 ; 21603234 ; 21603234 ; 21603234 ; 21771186 ; 21771186 ; 21771186 ; 21771186 ; 21171170 ; 21171170 ; 21171170 ; 21171170 ; 21501182 ; 21501182 ; 21501182 ; 21501182 ; 21601193) ; 21601193) ; 21601193) ; 21601193)
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/33804]
专题	合肥物质科学研究院_中科院固体物理研究所
作者单位	1.Chinese Acad Sci, Inst Solid State Phys, CAS Ctr Excellence Nanosci, Anhui Key Lab Nanomat & Nanotechnol,Key Lab Mat P, Hefei 230031, Anhui, Peoples R China 2.Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China 3.Tsinghua Univ, Tsinghua Univ Peking Univ Joint Ctr Life Sci, Sch Life Sci, Beijing 100084, Peoples R China 4.Tsinghua Univ, Sch Life Sci, MOE Key Lab Bioinformat, Beijing 100084, Peoples R China 5.Shanghai Jiao Tong Univ, Instrumental Anal Ctr, Shanghai 200240, Peoples R China
推荐引用方式 GB/T 7714	Zhuang, Shengli,Liao, Lingwen,Li, Man-Bo,et al. The fcc structure isomerization in gold nanoclusters[J]. NANOSCALE,2017,9(39):14809-14813.
APA	Zhuang, Shengli.,Liao, Lingwen.,Li, Man-Bo.,Yao, Chuanhao.,Zhao, Yan.,...&Wu, Zhikun.(2017).The fcc structure isomerization in gold nanoclusters.NANOSCALE,9(39),14809-14813.
MLA	Zhuang, Shengli,et al."The fcc structure isomerization in gold nanoclusters".NANOSCALE 9.39(2017):14809-14813.

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