High-Efficiency Co/CoxSy@S,N-Codoped Porous Carbon Electrocatalysts Fabricated from Controllably Grown Sulfur- and Nitrogen-Including Cobalt-Based MOFs for Rechargeable Zinc-Air Batteries

doi:10.1021/acsami.7b11101

CORC > 合肥物质科学研究院 > 中国科学院合肥物质科学研究院 > 中科院固体物理研究所

	High-Efficiency Co/CoxSy@S,N-Codoped Porous Carbon Electrocatalysts Fabricated from Controllably Grown Sulfur- and Nitrogen-Including Cobalt-Based MOFs for Rechargeable Zinc-Air Batteries
	Liu, Shengwen 1; Zhang, Xian1,2 ; Wang, Guozhong 1; Zhang, Yunxia 1; Zhang, Haimin 1
刊名	ACS APPLIED MATERIALS & INTERFACES
	2017-10-04
卷号	9 期号:39 页码:34269-34278
关键词	[Co(Tdc)(Bpy)](n) Solvent Effect Bifunctional Oxygen Electrocatalysts s Zn-air Battery n Dual Organic Ligands
DOI	10.1021/acsami.7b11101
文献子类	Article
英文摘要	Developing bifunctional oxygen electrocatalysts with superior catalytic activities of oxygen reduction reaction (ORR) and oxygen revolution reaction (OER) is crucial to their practical energy storage and conversion applications. In this work, we report the fabrication of Co/CoxSy@S,N-codoped porous carbon structures with various morphologies, specific surface areas, and pore structures, derived from controllably grown Co-based metalorganic frameworks with S- and N-containing organic ligands (thiophene-2,5-dicarboxylate, Tdc; and 4,4 '-bipyridine, bpy) utilizing solvent effect (e.g., water and methanol) under room temperature and hydrothermal conditions. The results demonstrate that Co/CoxSy@S,N-codoped carbon fibers fabricated at a pyrolytic temperature of 800 degrees C (Co/CoxSy@SNCF-800) from Co-MOFs fibers fabricated in methanol under hydrothermal conditions as electrocatalysts exhibit superior bifunctional ORR and OER activities in alkaline media, endowing them as air cathodic catalysts in rechargeable zincair batteries with high power density and good durability.
WOS关键词	METAL-ORGANIC FRAMEWORK ; OXYGEN REDUCTION REACTION ; BIFUNCTIONAL ELECTROCATALYSTS ; EVOLUTION REACTIONS ; HIGH-PERFORMANCE ; HYDROGEN EVOLUTION ; FREE CATALYSTS ; SULFIDE ; NANOCOMPOSITES ; NANOPARTICLES
WOS研究方向	Science & Technology - Other Topics ; Materials Science
语种	英语
WOS记录号	WOS:000412717600102
资助机构	National Natural Science Foundation of China(51672277) ; National Natural Science Foundation of China(51672277) ; National Natural Science Foundation of China(51672277) ; National Natural Science Foundation of China(51672277) ; CAS ; CAS ; CAS ; CAS ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; National Natural Science Foundation of China(51672277) ; National Natural Science Foundation of China(51672277) ; National Natural Science Foundation of China(51672277) ; National Natural Science Foundation of China(51672277) ; CAS ; CAS ; CAS ; CAS ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/33791]
专题	合肥物质科学研究院_中科院固体物理研究所
作者单位	1.Chinese Acad Sci, Inst Solid State Phys, Anhui Key Lab Nanomat & Nanotechnol, Key Lab Mat Phys,Ctr Environm & Energy Nanomat, Hefei 230031, Anhui, Peoples R China 2.Univ Sci & Technol China, Hefei 230026, Anhui, Peoples R China
推荐引用方式 GB/T 7714	Liu, Shengwen,Zhang, Xian,Wang, Guozhong,et al. High-Efficiency Co/CoxSy@S,N-Codoped Porous Carbon Electrocatalysts Fabricated from Controllably Grown Sulfur- and Nitrogen-Including Cobalt-Based MOFs for Rechargeable Zinc-Air Batteries[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9(39):34269-34278.
APA	Liu, Shengwen,Zhang, Xian,Wang, Guozhong,Zhang, Yunxia,&Zhang, Haimin.(2017).High-Efficiency Co/CoxSy@S,N-Codoped Porous Carbon Electrocatalysts Fabricated from Controllably Grown Sulfur- and Nitrogen-Including Cobalt-Based MOFs for Rechargeable Zinc-Air Batteries.ACS APPLIED MATERIALS & INTERFACES,9(39),34269-34278.
MLA	Liu, Shengwen,et al."High-Efficiency Co/CoxSy@S,N-Codoped Porous Carbon Electrocatalysts Fabricated from Controllably Grown Sulfur- and Nitrogen-Including Cobalt-Based MOFs for Rechargeable Zinc-Air Batteries".ACS APPLIED MATERIALS & INTERFACES 9.39(2017):34269-34278.