Cr(VI) Reduction and Immobilization by Core-Double-Shell Structured Magnetic Polydopamine@Zeolitic Idazolate Frameworks-8 Microspheres | |
Zhu, Kairuo1,2; Chen, Changlun1,2,3; Xu, Huan1; Gao, Yang1; Tan, Xiaoli1; Alsaedi, Ahmed3; Hayat, Tasawar3,4 | |
刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
![]() |
2017-08-01 | |
卷号 | 5期号:8页码:6795-6802 |
关键词 | Mp@zif-8 Hydrid Microsphere Cr(Vi) Adsorption Reduction |
DOI | 10.1021/acssuschemeng.7b01036 |
文献子类 | Article |
英文摘要 | A well-defined core-double-shell structured magnetic polydopamine@zeolitic idazolate frameworks-8 (MP@ZIF-8) hydrid microsphere consisting of the core of magnetic Fe3O4 nanoparticles, the inner shell of a polydopamine layer, and the outer shell of a porous ZIF-8 nanocrystal was prepared through a facile and green approach to achieve synergistic reduction and adsorptive removal of Cr(VI). The microsphere property was characterized methodically. The batch adsorption experiments showed that the MP@ZIF-8 exhibited high efficiency in the Cr(VI) removal from aqueous solutions, affording Cr(VI) removal capacity of 136.56 mg g(-1), surpassing pristine MP (92.27 mg g(-1)). The pseudo-second-order model fitted the Cr(VI) removal kinetics well. Cr(VI) removal on the MP@ZIF-8 relied highly on pH values. More significantly, with the reduction of nitrogen atom group on ZIF-8 and PDA, Cr(VI) was easily converted into low toxicity Cr(III) and then immobilized on the MP@ZIF-8. Thus, the hybrid microspheres provided excellent adsorptive activity in treating Cr-contaminated wastewater. |
WOS关键词 | GRAPHENE OXIDE NANOSHEETS ; METAL-ORGANIC FRAMEWORK ; IMIDAZOLATE FRAMEWORK-8 ; AQUEOUS-SOLUTION ; COMPOSITE MICROSPHERES ; HEXAVALENT CHROMIUM ; HIGH-PERFORMANCE ; HIGH-EFFICIENCY ; HUMIC-ACID ; REMOVAL |
WOS研究方向 | Chemistry ; Engineering |
语种 | 英语 |
WOS记录号 | WOS:000407410900049 |
资助机构 | National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; National Natural Science Foundation of China(21477133 ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) ; U1607102) |
内容类型 | 期刊论文 |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/33659] ![]() |
专题 | 合肥物质科学研究院_中科院等离子体物理研究所 |
作者单位 | 1.Chinese Acad Sci, Inst Plasma Phys, POB 1126, Hefei 230031, Anhui, Peoples R China 2.Soochow Univ, Jiangsu Higher Educ Inst, Collaborat Innovat Ctr Radiat Med, Suzhou 215123, Peoples R China 3.King Abdulaziz Univ, NAAM Res Grp, Jeddah 21589, Saudi Arabia 4.Quaid I Azam Univ, Dept Math, Islamabad 44000, Pakistan |
推荐引用方式 GB/T 7714 | Zhu, Kairuo,Chen, Changlun,Xu, Huan,et al. Cr(VI) Reduction and Immobilization by Core-Double-Shell Structured Magnetic Polydopamine@Zeolitic Idazolate Frameworks-8 Microspheres[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2017,5(8):6795-6802. |
APA | Zhu, Kairuo.,Chen, Changlun.,Xu, Huan.,Gao, Yang.,Tan, Xiaoli.,...&Hayat, Tasawar.(2017).Cr(VI) Reduction and Immobilization by Core-Double-Shell Structured Magnetic Polydopamine@Zeolitic Idazolate Frameworks-8 Microspheres.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,5(8),6795-6802. |
MLA | Zhu, Kairuo,et al."Cr(VI) Reduction and Immobilization by Core-Double-Shell Structured Magnetic Polydopamine@Zeolitic Idazolate Frameworks-8 Microspheres".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 5.8(2017):6795-6802. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论