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	High performance anion exchange ionomer for anion exchange membrane fuel cells
	Gao, Xueqiang1,2; Yu, Hongmei2; Jia, Jia1,2; Hao, Jinkai1,2; Xie, Feng1,2; Chi, Jun1,2; Qin, Bowen1,2; Fu, Li1,2; Song, Wei2; Shao, Zhigang2
刊名	RSC ADVANCES
	2017
卷号	7页码:19153-19161
DOI	10.1039/c7ra01980g
英文摘要	The anion exchange ionomer incorporated into the electrodes of an anion exchange membrane fuel cell (AEMFC) enhances anion transport in the catalyst layer of the electrode, and thus improves performance and durability of the AEMFC. In this work, a novel ionomer based on a triblock copolymer with high conductivity and good durability is synthesized successfully. The spectroscopy (such as H-1-NMR, FT-IR) results of the ionomer indicate that the functional group is grafted onto the poly(styrene-ethylene/ butylene-styrene) (SEBS) successfully and the OH(-)conductivity of the ionomer is 30 mS cm(-1) at 75(-)C. Besides, quaternary ammonium SEBS (QASEBS) is used as the ionomer in a H-2/O-2 AEMFC and exhibits a significant durability of 500 h at a constant current density of 100 mA cm(-2), moreover, the degradation rate of voltage is only 0.22 mV h(-1) during the 500 h durability test. In addition, the peak power density of the membrane electrode assembly (MEA) with the QASEBS ionomer reaches 375 mW cm (2) at 50 degrees C, which is 3 times than that of the MEA using the commercially available Acta I-2 ionomer (124 mW cm(-2)) for comparison.
语种	英语
WOS记录号	WOS:000399240400041
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/152321]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Fuel Cell Syst & Engn Lab, 457 Zhongshan Rd, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Gao, Xueqiang,Yu, Hongmei,Jia, Jia,et al. High performance anion exchange ionomer for anion exchange membrane fuel cells[J]. RSC ADVANCES,2017,7:19153-19161.
APA	Gao, Xueqiang.,Yu, Hongmei.,Jia, Jia.,Hao, Jinkai.,Xie, Feng.,...&Shao, Zhigang.(2017).High performance anion exchange ionomer for anion exchange membrane fuel cells.RSC ADVANCES,7,19153-19161.
MLA	Gao, Xueqiang,et al."High performance anion exchange ionomer for anion exchange membrane fuel cells".RSC ADVANCES 7(2017):19153-19161.

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