Cruciform Electron Acceptors Based on Tetraindeno-Fused Spirofluorene

doi:10.1021/acs.cgd.7b00272

	Cruciform Electron Acceptors Based on Tetraindeno-Fused Spirofluorene
	Xia, Debin 1,4; Guo, Xin 3; Wagner, Manfred 4; Baumgarten, Martin 4; Schollmeyer, Dieter 2; Muellen, Klaus 2
刊名	CRYSTAL GROWTH & DESIGN
	2017-05-01
卷号	17 页码:2816-2821
DOI	10.1021/acs.cgd.7b00272
英文摘要	Two cruciform tetraindenospirofluorene-based acceptors embedding carbonyl (Spiro-4O) and dicyano-vinylene (Spiro-8CN) functionalities are synthesized in high yields. Single-crystal X-ray analysis reveals a one-dimensional pi-pi stacking arrangement for Spiro-4O, while Spiro-8CN adopts a unique two-dimensional isotropic a-interaction. Cyclic voltammetry suggests a high electron affinity of -3.76 eV for Spiro-8CN. Such a packing motif and low LUMO energy for Spiro-8CN are important for bulk electron transport.
语种	英语
WOS记录号	WOS:000400802500060
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/152318]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Harbin Inst Technol, Sch Chem & Chem Engn, MIIT Key Lab Crit Mat Technol New Energy Convers, Harbin 150001, Peoples R China 2.Johannes Gutenberg Univ Mainz, Duesbergweg 10-14, D-55128 Mainz, Germany 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 4.Max Planck Inst Polymer Res, Ackermannweg 10, D-55128 Mainz, Germany
推荐引用方式 GB/T 7714	Xia, Debin,Guo, Xin,Wagner, Manfred,et al. Cruciform Electron Acceptors Based on Tetraindeno-Fused Spirofluorene[J]. CRYSTAL GROWTH & DESIGN,2017,17:2816-2821.
APA	Xia, Debin,Guo, Xin,Wagner, Manfred,Baumgarten, Martin,Schollmeyer, Dieter,&Muellen, Klaus.(2017).Cruciform Electron Acceptors Based on Tetraindeno-Fused Spirofluorene.CRYSTAL GROWTH & DESIGN,17,2816-2821.
MLA	Xia, Debin,et al."Cruciform Electron Acceptors Based on Tetraindeno-Fused Spirofluorene".CRYSTAL GROWTH & DESIGN 17(2017):2816-2821.