State-of-the-Art Multifunctional Heterogeneous POP Catalyst for Cooperative Transformation of CO2 to Cyclic Carbonates

doi:10.1021/acssuschemeng.7b00947

	State-of-the-Art Multifunctional Heterogeneous POP Catalyst for Cooperative Transformation of CO2 to Cyclic Carbonates
	Wang, Wenlong 2; Wang, Yuqing 2,3; Li, Cunyao 2; Yan, Li 2; Jiang, Miao 2; Ding, Yunjie 1,2
刊名	ACS SUSTAINABLE CHEMISTRY & ENGINEERING
	2017-06-01
卷号	5 页码:4523-4528
关键词	Carbon Dioxide Polymeric Catalyst Heterogeneous Catalyst Cooperative Catalysis Cyclic Carbonates
DOI	10.1021/acssuschemeng.7b00947
英文摘要	A single-component multifunctional catalyst (denoted as Mg-por/pho@POP) based on a magnesium porphyrin and phosphonium salt-integrated porous organic polymer (POP) was afforded via a solvothermal synthetic technique for cyclic carbonate production which uses epoxides and CO2. In consequence of the cooperative (or synergistic) effect of a phosphonium salt and homogeneously dispersed magnesium porphyrin moiety, which is possibly reinforced through the flexible frameworks and confined microporous structure, this powerful catalyst offered the highest activity of a heterogeneous catalyst within the context of cyclic carbonates synthesis from epoxide and CO2 (turnover frequencies up to 15,600 h(-1)) without the addition of co-catalysts. More surprisingly, very promising turnover numbers (TONs) of 14,400 and 4200 were realized at very mild temperatures of 25 and 40 degrees C. Moreover, Mg-por/pho@POP can be simply recovered and reused at least five times.
语种	英语
WOS记录号	WOS:000402950000007
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/152184]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, 19 Yuquan Rd, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Wang, Wenlong,Wang, Yuqing,Li, Cunyao,et al. State-of-the-Art Multifunctional Heterogeneous POP Catalyst for Cooperative Transformation of CO2 to Cyclic Carbonates[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2017,5:4523-4528.
APA	Wang, Wenlong,Wang, Yuqing,Li, Cunyao,Yan, Li,Jiang, Miao,&Ding, Yunjie.(2017).State-of-the-Art Multifunctional Heterogeneous POP Catalyst for Cooperative Transformation of CO2 to Cyclic Carbonates.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,5,4523-4528.
MLA	Wang, Wenlong,et al."State-of-the-Art Multifunctional Heterogeneous POP Catalyst for Cooperative Transformation of CO2 to Cyclic Carbonates".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 5(2017):4523-4528.