Copper-catalyzed intermolecular asymmetric propargylic dearomatization of phenol derivatives

doi:10.1039/c7cc03034g

	Copper-catalyzed intermolecular asymmetric propargylic dearomatization of phenol derivatives
	Shao, Long 1,2; Hu, Xiang-Ping 1
刊名	CHEMICAL COMMUNICATIONS
	2017-07-25
卷号	53 期号:58 页码:8192-8195
DOI	10.1039/c7cc03034g
英文摘要	A copper-catalyzed intermolecular asymmetric propargylic dearomatization of phenol derivatives has been realized. Under the catalysis of Cu(OTf)center dot 1/2C(6)H(6) decorated with a chiral tridentate ketimine P,N,N-ligand, the dearomatization reaction proceeded smoothly with excellent control of chemo-, regio-, and enantio-selectivities, thus providing a variety of optically active cyclohexadienone derivatives with up to > 99% ee.
语种	英语
WOS记录号	WOS:000405679100020
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/152048]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Shao, Long,Hu, Xiang-Ping. Copper-catalyzed intermolecular asymmetric propargylic dearomatization of phenol derivatives[J]. CHEMICAL COMMUNICATIONS,2017,53(58):8192-8195.
APA	Shao, Long,&Hu, Xiang-Ping.(2017).Copper-catalyzed intermolecular asymmetric propargylic dearomatization of phenol derivatives.CHEMICAL COMMUNICATIONS,53(58),8192-8195.
MLA	Shao, Long,et al."Copper-catalyzed intermolecular asymmetric propargylic dearomatization of phenol derivatives".CHEMICAL COMMUNICATIONS 53.58(2017):8192-8195.