Carbon-embedded Ni nanocatalysts derived from MOFs by a sacrificial template method for efficient hydrogenation of furfural to tetrahydrofurfuryl alcohol

doi:10.1039/c7dt00628d

CORC > 合肥物质科学研究院 > 中国科学院合肥物质科学研究院 > 中科院固体物理研究所

	Carbon-embedded Ni nanocatalysts derived from MOFs by a sacrificial template method for efficient hydrogenation of furfural to tetrahydrofurfuryl alcohol
	Su, Yanping 1,2; Chen, Chun 1; Zhu, Xiaoguang 1; Zhang, Yong1,2 ; Gong, Wanbing 1,2; Zhang, Haimin 1; Zhao, Huijun 1,3; Wang, Guozhong 1
刊名	DALTON TRANSACTIONS
	2017-05-21
卷号	46 期号:19 页码:6358-6365
DOI	10.1039/c7dt00628d
文献子类	Article
英文摘要	We report a fast and simple method for the synthesis of Ni-based metal-organic-frameworks (Ni-MOFs). Due to the existence of nickel ions and an organic ligand, the MOFs are employed as a sacrificial template for the facile preparation of carbon-embedded Ni (Ni/C) catalysts by a direct thermal decomposition method. The obtained Ni/C catalysts exhibit excellent catalytic activity for selectively transforming furfural (FAL) to tetrahydrofurfuryl alcohol (THFOL) due to the Ni nanoparticles (NPs) embedded uniformly in the ligand-derived carbon. The exemplified results illustrate that the catalytic performance of the Ni/C catalyst is greatly affected by the calcination conditions (temperature and time), composition of the Ni-MOF precursor and the catalysis conditions. The conversion of FAL and selectivity of THFOL both reached 100% under the conditions of 120 degrees C, 1 MPa H-2 pressure and 120 min of hydrogenation over the Ni/C-500 catalyst, derived from the pyrolysis of Ni-MOFs (Ni : BTC mole ratio of 1.0) at 500 degrees C for 120 min, which exhibits an average nanoparticle size of similar to 14 nm and uniform dispersion, and the highest BET surface area (similar to 92 m(2) g(-1)) among all investigated Ni/C catalysts. This facilely prepared heterogeneous catalyst would be very promising for the replacement of noble metal catalysts for the efficient catalytic conversion of biomass-derived feedstocks into value-added chemicals.
WOS关键词	METAL-ORGANIC FRAMEWORKS ; HIGHLY SELECTIVE HYDROGENATION ; OXIDATIVE ESTERIFICATION ; CATALYTIC-HYDROGENATION ; OXYGEN REDUCTION ; GOLD CATALYSTS ; NANOPARTICLES ; CHEMICALS ; BIOMASS ; CYCLOPENTANONE
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000401526700024
资助机构	Natural Science Foundation of China(51502297 ; Natural Science Foundation of China(51502297 ; Natural Science Foundation of China(51502297 ; Natural Science Foundation of China(51502297 ; Instrument Developing Project of the Chinese Academy of Sciences(yz201421) ; Instrument Developing Project of the Chinese Academy of Sciences(yz201421) ; Instrument Developing Project of the Chinese Academy of Sciences(yz201421) ; Instrument Developing Project of the Chinese Academy of Sciences(yz201421) ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; 51372248 ; 51372248 ; 51372248 ; 51372248 ; 51432009) ; 51432009) ; 51432009) ; 51432009) ; Natural Science Foundation of China(51502297 ; Natural Science Foundation of China(51502297 ; Natural Science Foundation of China(51502297 ; Natural Science Foundation of China(51502297 ; Instrument Developing Project of the Chinese Academy of Sciences(yz201421) ; Instrument Developing Project of the Chinese Academy of Sciences(yz201421) ; Instrument Developing Project of the Chinese Academy of Sciences(yz201421) ; Instrument Developing Project of the Chinese Academy of Sciences(yz201421) ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; 51372248 ; 51372248 ; 51372248 ; 51372248 ; 51432009) ; 51432009) ; 51432009) ; 51432009)
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/31945]
专题	合肥物质科学研究院_中科院固体物理研究所
作者单位	1.Chinese Acad Sci, Key Lab Mat Phys, Ctr Environm & Energy Nanomat,Inst Solid State Ph, Anhui Key Lab Nanomat & Nanotechnol,CAS Ctr Excel, Hefei 230031, Peoples R China 2.Univ Sci & Technol China, Hefei 230026, Anhui, Peoples R China 3.Griffith Univ, Ctr Clean Environm & Energy, Gold Coast Campus, Southport, Qld 4222, Australia
推荐引用方式 GB/T 7714	Su, Yanping,Chen, Chun,Zhu, Xiaoguang,et al. Carbon-embedded Ni nanocatalysts derived from MOFs by a sacrificial template method for efficient hydrogenation of furfural to tetrahydrofurfuryl alcohol[J]. DALTON TRANSACTIONS,2017,46(19):6358-6365.
APA	Su, Yanping.,Chen, Chun.,Zhu, Xiaoguang.,Zhang, Yong.,Gong, Wanbing.,...&Wang, Guozhong.(2017).Carbon-embedded Ni nanocatalysts derived from MOFs by a sacrificial template method for efficient hydrogenation of furfural to tetrahydrofurfuryl alcohol.DALTON TRANSACTIONS,46(19),6358-6365.
MLA	Su, Yanping,et al."Carbon-embedded Ni nanocatalysts derived from MOFs by a sacrificial template method for efficient hydrogenation of furfural to tetrahydrofurfuryl alcohol".DALTON TRANSACTIONS 46.19(2017):6358-6365.