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	Engineering stepped edge surface structures of MoS2 sheet stacks to accelerate the hydrogen evolution reaction
	Hu, Jue1; Huang, Bolong2; Zhang, Chengxu3,4; Wang, Zilong1; An, Yiming1; Zhou, Dan1; Lin, He1; Leung, Michael K. H.3; Yang, Shihe1
刊名	ENERGY & ENVIRONMENTAL SCIENCE
	2017-02-01
卷号	10期号:2页码:593-603
DOI	10.1039/c6ee03629e
文献子类	Article
英文摘要	Two-dimensional molybdenum sulfide is an attractive noble-metal-free electrocatalyst for the hydrogen evolution reaction (HER). Significant efforts have been made to increase the number of exposed edge sites. However, little attention has been paid to devising edge surface structures of MoS2 sheet stacks to promote the HER kinetics. Herein we report the first demonstration of significantly enhanced HER kinetics by controllably fabricating a stepped MoS2 surface structure. Vertical arrays of MoS2 sheets terminated with such a stepped surface structure have proved to be an outstanding HER electrocatalyst with an overpotential of 104 mV at 10 mA cm(-2), an exchange current density of 0.2 mA cm(-2) and high stability. Experimental and theoretical results indicate that the enhanced electrocatalytic activity of the vertical MoS2 arrays is associated with the unique vertically terminated, highly exposed, stepped surface structure with a nearly thermoneutral H-adsorption energy. This work opens a new avenue to designing and developing layered materials for electrochemical energy applications.
WOS关键词	ENHANCED ELECTROCATALYTIC ACTIVITY ; METAL DICHALCOGENIDE NANOSHEETS ; ULTRATHIN NANOSHEETS ; OXYGEN REDUCTION ; MOLYBDENUM SULFIDES ; CATALYTIC-ACTIVITY ; EFFICIENT ; NANOPARTICLES ; TRANSITION ; GROWTH
WOS研究方向	Chemistry ; Energy & Fuels ; Engineering ; Environmental Sciences & Ecology
语种	英语
WOS记录号	WOS:000395679100018
资助机构	NSFC/Hong Kong RGC Research Scheme(N_HKUST610/14) ; NSFC/Hong Kong RGC Research Scheme(N_HKUST610/14) ; NSFC/Hong Kong RGC Research Scheme(N_HKUST610/14) ; NSFC/Hong Kong RGC Research Scheme(N_HKUST610/14) ; NSFC/Hong Kong RGC Research Scheme(N_HKUST610/14) ; NSFC/Hong Kong RGC Research Scheme(N_HKUST610/14) ; NSFC/Hong Kong RGC Research Scheme(N_HKUST610/14) ; NSFC/Hong Kong RGC Research Scheme(N_HKUST610/14) ; RGC of Hong Kong(16300915) ; RGC of Hong Kong(16300915) ; RGC of Hong Kong(16300915) ; RGC of Hong Kong(16300915) ; RGC of Hong Kong(16300915) ; RGC of Hong Kong(16300915) ; RGC of Hong Kong(16300915) ; RGC of Hong Kong(16300915) ; National Nature Science Foundation of Anhui Province(1508085QA10) ; National Nature Science Foundation of Anhui Province(1508085QA10) ; National Nature Science Foundation of Anhui Province(1508085QA10) ; National Nature Science Foundation of Anhui Province(1508085QA10) ; National Nature Science Foundation of Anhui Province(1508085QA10) ; National Nature Science Foundation of Anhui Province(1508085QA10) ; National Nature Science Foundation of Anhui Province(1508085QA10) ; National Nature Science Foundation of Anhui Province(1508085QA10) ; Youth Innovation Promotion Association of Chinese Academy of Sciences(2015265) ; Youth Innovation Promotion Association of Chinese Academy of Sciences(2015265) ; Youth Innovation Promotion Association of Chinese Academy of Sciences(2015265) ; Youth Innovation Promotion Association of Chinese Academy of Sciences(2015265) ; Youth Innovation Promotion Association of Chinese Academy of Sciences(2015265) ; Youth Innovation Promotion Association of Chinese Academy of Sciences(2015265) ; Youth Innovation Promotion Association of Chinese Academy of Sciences(2015265) ; Youth Innovation Promotion Association of Chinese Academy of Sciences(2015265) ; NSFC/Hong Kong RGC Research Scheme(N_HKUST610/14) ; NSFC/Hong Kong RGC Research Scheme(N_HKUST610/14) ; NSFC/Hong Kong RGC Research Scheme(N_HKUST610/14) ; NSFC/Hong Kong RGC Research Scheme(N_HKUST610/14) ; NSFC/Hong Kong RGC Research Scheme(N_HKUST610/14) ; NSFC/Hong Kong RGC Research Scheme(N_HKUST610/14) ; NSFC/Hong Kong RGC Research Scheme(N_HKUST610/14) ; NSFC/Hong Kong RGC Research Scheme(N_HKUST610/14) ; RGC of Hong Kong(16300915) ; RGC of Hong Kong(16300915) ; RGC of Hong Kong(16300915) ; RGC of Hong Kong(16300915) ; RGC of Hong Kong(16300915) ; RGC of Hong Kong(16300915) ; RGC of Hong Kong(16300915) ; RGC of Hong Kong(16300915) ; National Nature Science Foundation of Anhui Province(1508085QA10) ; National Nature Science Foundation of Anhui Province(1508085QA10) ; National Nature Science Foundation of Anhui Province(1508085QA10) ; National Nature Science Foundation of Anhui Province(1508085QA10) ; National Nature Science Foundation of Anhui Province(1508085QA10) ; National Nature Science Foundation of Anhui Province(1508085QA10) ; National Nature Science Foundation of Anhui Province(1508085QA10) ; National Nature Science Foundation of Anhui Province(1508085QA10) ; Youth Innovation Promotion Association of Chinese Academy of Sciences(2015265) ; Youth Innovation Promotion Association of Chinese Academy of Sciences(2015265) ; Youth Innovation Promotion Association of Chinese Academy of Sciences(2015265) ; Youth Innovation Promotion Association of Chinese Academy of Sciences(2015265) ; Youth Innovation Promotion Association of Chinese Academy of Sciences(2015265) ; Youth Innovation Promotion Association of Chinese Academy of Sciences(2015265) ; Youth Innovation Promotion Association of Chinese Academy of Sciences(2015265) ; Youth Innovation Promotion Association of Chinese Academy of Sciences(2015265)
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/31699]
专题	合肥物质科学研究院_中科院等离子体物理研究所
作者单位	1.Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China 2.Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Kowloon, Hong Kong, Peoples R China 3.City Univ Hong Kong, Sch Energy & Environm, Abil R&D Energy Res Ctr, Hong Kong, Hong Kong, Peoples R China 4.Chinese Acad Sci, Inst Plasma Phys, Hefei, Anhui, Peoples R China
推荐引用方式 GB/T 7714	Hu, Jue,Huang, Bolong,Zhang, Chengxu,et al. Engineering stepped edge surface structures of MoS2 sheet stacks to accelerate the hydrogen evolution reaction[J]. ENERGY & ENVIRONMENTAL SCIENCE,2017,10(2):593-603.
APA	Hu, Jue.,Huang, Bolong.,Zhang, Chengxu.,Wang, Zilong.,An, Yiming.,...&Yang, Shihe.(2017).Engineering stepped edge surface structures of MoS2 sheet stacks to accelerate the hydrogen evolution reaction.ENERGY & ENVIRONMENTAL SCIENCE,10(2),593-603.
MLA	Hu, Jue,et al."Engineering stepped edge surface structures of MoS2 sheet stacks to accelerate the hydrogen evolution reaction".ENERGY & ENVIRONMENTAL SCIENCE 10.2(2017):593-603.

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