High-performance bifunctional oxygen electrocatalyst derived from iron and nickel substituted perfluorosulfonic acid/polytetrafluoroethylene copolymer
Jiang, Qike3; Sun, Shucheng3; Bao, Xinhe1,3; Miao, Shu3; Wu, Haihua1,2; Wang, Jing1; Wang, Guoxiong1; Cai, Fan1,2; Ye, Yifan1,2
刊名NANO ENERGY
2016-12-01
卷号30页码:801-809
关键词Perfluorosulfonic acid/polytetrafluoroethylene copolymer Iron-nickel substitution Nitrogen-fluorine co-doped carbon Iron-nickel alloy Bifunctional oxygen electrocatalyst
英文摘要Heteroatom-doped carbon materials and 3d transition metals have shown high activity and durability for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER), respectively, but poor bifunctionality. Herein, we use iron and nickel substituted perfluorosulfonic acid/polytetrafluoroethylene copolymer with uniform distribution and conveniently adjustable ratios of metal ions as the pyrolysis precursor to synthesize nitrogen and fluorine co-doped carbon supported FeNi hybrid material. The hybrid material integrates ORR and OER active components together, and exhibits excellent bifunctionality in alkaline medium, demonstrating high performance and cycling durability in rechargeable zinc air battery. (C) 2016 Elsevier Ltd. All rights reserved.
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
研究领域[WOS]Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
关键词[WOS]NITROGEN-DOPED CARBON ; METAL-AIR BATTERIES ; REDUCTION REACTION ; FUEL-CELLS ; EVOLUTION REACTION ; WATER OXIDATION ; ACTIVE-SITES ; NANOPARTICLES ; CATALYSTS ; GRAPHENE
收录类别SCI
语种英语
WOS记录号WOS:000390636100091
内容类型期刊论文
源URL[http://cas-ir.dicp.ac.cn/handle/321008/150512]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Ctr Excellence Nanosci, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Jiang, Qike,Sun, Shucheng,Bao, Xinhe,et al. High-performance bifunctional oxygen electrocatalyst derived from iron and nickel substituted perfluorosulfonic acid/polytetrafluoroethylene copolymer[J]. NANO ENERGY,2016,30:801-809.
APA Jiang, Qike.,Sun, Shucheng.,Bao, Xinhe.,Miao, Shu.,Wu, Haihua.,...&Ye, Yifan.(2016).High-performance bifunctional oxygen electrocatalyst derived from iron and nickel substituted perfluorosulfonic acid/polytetrafluoroethylene copolymer.NANO ENERGY,30,801-809.
MLA Jiang, Qike,et al."High-performance bifunctional oxygen electrocatalyst derived from iron and nickel substituted perfluorosulfonic acid/polytetrafluoroethylene copolymer".NANO ENERGY 30(2016):801-809.
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