Aromatic Tetralithiodigalloles with a Ga-Ga Bond: Synthesis and Structural Characterization

	Aromatic Tetralithiodigalloles with a Ga-Ga Bond: Synthesis and Structural Characterization
	Zhang, Wen-Xiong 2; Zhang, Yongliang 2; Chi, Yue 2; Wei, Junnian 2; Yang, Qi 2; Yang, Zhenqiang 1; Chen, Hui 1; Yang, Ruina 1; Xi, Zhenfeng 1,2
刊名	ORGANOMETALLICS
	2017-08-14
卷号	36 期号:15 页码:2982-2986
英文摘要	Aromatic 1,1,2,2-tetralithiodigalloles 5 with a Ga-Ga bond were realized. Reaction of 1,4-dilithio-1,3-butadienes 6 with 0.5 equiv of GaCl3 afforded lithium spirogallane ate complexes 7 in excellent isolated yields. Reduction of the above ate complexes 7 with an excess amount of lithium generated the 1,1,2,2-tetralithiodigalloles 5 in moderate isolated yields. The structures of compounds 5 and 7 were both determined by single-crystal X-ray structural analysis. The 1,1,2,2-tetralithiodigalloles 5 contained two aromatic dilithiogalloles connected by a Ga-Ga bond. The aromaticity of 5 was confirmed by both experimental measurements (X-ray structural analysis, NMR spectroscopy) and theoretical analysis (ISE, NICS).
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Inorganic & Nuclear ; Chemistry, Organic
研究领域[WOS]	Chemistry
关键词[WOS]	IN-IN BONDS ; MOLECULAR-STRUCTURE ; GALLIUM-GALLIUM ; AL-AL ; ORGANOELEMENT COMPOUNDS ; STANNOLE DIANION ; TRANSITION-METAL ; CHEMISTRY ; METALLABENZENES ; COMPLEXES
收录类别	SCI
语种	英语
WOS记录号	WOS:000407869100034
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/149948]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Henan Acad Sci, Henan Inst Chem Co Ltd, Zhengzhou 450002, Henan, Peoples R China 2.Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, BNLMS,Minist Educ, Beijing 100871, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Wen-Xiong,Zhang, Yongliang,Chi, Yue,et al. Aromatic Tetralithiodigalloles with a Ga-Ga Bond: Synthesis and Structural Characterization[J]. ORGANOMETALLICS,2017,36(15):2982-2986.
APA	Zhang, Wen-Xiong.,Zhang, Yongliang.,Chi, Yue.,Wei, Junnian.,Yang, Qi.,...&Xi, Zhenfeng.(2017).Aromatic Tetralithiodigalloles with a Ga-Ga Bond: Synthesis and Structural Characterization.ORGANOMETALLICS,36(15),2982-2986.
MLA	Zhang, Wen-Xiong,et al."Aromatic Tetralithiodigalloles with a Ga-Ga Bond: Synthesis and Structural Characterization".ORGANOMETALLICS 36.15(2017):2982-2986.