Access to Substituted Propenoic Acids via Rh(III)-Catalyzed C-H Allylation of (Hetero)Arenes with Methyleneoxetanones

	Access to Substituted Propenoic Acids via Rh(III)-Catalyzed C-H Allylation of (Hetero)Arenes with Methyleneoxetanones
	Zheng, Guangfan 1; Xia, Jintao 1,2; Kong, Lingheng 1,2; Zhou, Xukai 1,2; Li, Xingwei 1
刊名	ORGANIC LETTERS
	2017-11-03
卷号	19 期号:21 页码:5972-5975
英文摘要	An efficient synthesis of disubstituted acrylic acids has been realized via Rh(III)-catalyzed C-H activation of (hetero)arenes and coupling with four-membered methyleneoxetanones under redox-neutral conditions. In most cases, the reactions are silver-free, and the products are exclusively E-selective with a broad substrate scope. The transformation proceeds via ortho C-H activation followed by selective olefin insertion and beta-oxygen elimination.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Organic
研究领域[WOS]	Chemistry
关键词[WOS]	PALLADIUM-CATALYZED HYDROCARBOXYLATION ; CARBON-DIOXIDE ; FORMIC-ACID ; REGIOSELECTIVE HYDROCARBOXYLATION ; RHODIUM CATALYSIS ; CARBOXYLIC-ACIDS ; ALLYLIC ALCOHOLS ; BOND ACTIVATION ; ARENES ; ALKYNES
收录类别	SCI
语种	英语
WOS记录号	WOS:000414723900066
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/149683]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zheng, Guangfan,Xia, Jintao,Kong, Lingheng,et al. Access to Substituted Propenoic Acids via Rh(III)-Catalyzed C-H Allylation of (Hetero)Arenes with Methyleneoxetanones[J]. ORGANIC LETTERS,2017,19(21):5972-5975.
APA	Zheng, Guangfan,Xia, Jintao,Kong, Lingheng,Zhou, Xukai,&Li, Xingwei.(2017).Access to Substituted Propenoic Acids via Rh(III)-Catalyzed C-H Allylation of (Hetero)Arenes with Methyleneoxetanones.ORGANIC LETTERS,19(21),5972-5975.
MLA	Zheng, Guangfan,et al."Access to Substituted Propenoic Acids via Rh(III)-Catalyzed C-H Allylation of (Hetero)Arenes with Methyleneoxetanones".ORGANIC LETTERS 19.21(2017):5972-5975.