Porphyrin-poly(arylene ether sulfone) covalently functionalized multi-walled carbon nanotubes: synthesis and enhanced broadband nonlinear optical properties
Wang, Jun; Du, Yinlong; Dong, Ningning; Zhang, Menghan; Zhang, Yunhe; Luan, Jiashuang; Lu, Yaning; Zhang, Shuling; Sun, Ningwei; Wang, Guibin
刊名RSC Adv.
2016
卷号6期号:79页码:75530
通讯作者wgb@jlu.edu.cn
英文摘要A novel multi-walled carbon nanotube (MWNT) hybrid was synthesized by covalently attaching a porphyrinated poly(arylene ether sulfone) onto the surface of carbon nanotubes. The polymer functionalized nanotube exhibited excellent solubility in organic solvents, and the weight% of MWNTs in the resulting hybrid was found to be 36%. Considerable fluorescence quenching and shortened fluorescence lifetime were observed in the MWNT hybrid due to the photo-induced electron/energy transfer behavior from porphyrin moieties to MWNTs. Z-scan measurements demonstrated the improved broadband nonlinear optical performance of the MWNT hybrid at both 532 and 1064 nm in nanoseconds, which is attributed to the accumulation effect of nonlinear absorption and scattering, and a remarkable photo-induced electron/energy transfer process. Meanwhile, the MWNT hybrid can be homogeneously dispersed in a polymer matrix, further fabricated into a uniform film with high transparency and ultrafast optical limiting response under femtosecond laser pulses.
收录类别SCI
资助信息Ph.D. Program Foundation of the Ministry of Education of China [20120061110017]; Jilin Science and Technology Development Plan Program of China [20150204001GX]; National Natural Science Foundation of China [61308087, 61522510]; External Cooperation Progra
WOS记录号WOS:000381513800065
内容类型期刊论文
源URL[http://ir.siom.ac.cn/handle/181231/28157]  
专题上海光学精密机械研究所_中科院强激光材料重点实验室
作者单位中国科学院上海光学精密机械研究所
推荐引用方式
GB/T 7714
Wang, Jun,Du, Yinlong,Dong, Ningning,et al. Porphyrin-poly(arylene ether sulfone) covalently functionalized multi-walled carbon nanotubes: synthesis and enhanced broadband nonlinear optical properties[J]. RSC Adv.,2016,6(79):75530.
APA Wang, Jun.,Du, Yinlong.,Dong, Ningning.,Zhang, Menghan.,Zhang, Yunhe.,...&Wang, Guibin.(2016).Porphyrin-poly(arylene ether sulfone) covalently functionalized multi-walled carbon nanotubes: synthesis and enhanced broadband nonlinear optical properties.RSC Adv.,6(79),75530.
MLA Wang, Jun,et al."Porphyrin-poly(arylene ether sulfone) covalently functionalized multi-walled carbon nanotubes: synthesis and enhanced broadband nonlinear optical properties".RSC Adv. 6.79(2016):75530.
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