Excitonic and vibrational coherence in artificial photosynthetic systems studied by negative-time ultrafast laser spectroscopy | |
Han, Dongjia; Xue, Bing; Du, Juan; Kobayashi, Takayoshi; Miyatake, Tomohiro; Tamiaki, Hitoshi; Xing, Xin; Yuan, Wei; Li, Yanyan; Leng, Yuxin | |
刊名 | Phys. Chem. Chem. Phys.
![]() |
2016 | |
卷号 | 18期号:35页码:24252 |
通讯作者 | dujuan@mail.siom.ac.cn ; lengyuxin@mail.siom.ac.cn |
英文摘要 | Quantum coherences between excitonic states are believed to have a substantial impact on excitation energy transfer in photosynthetic systems. Here, the excitonic and vibrational coherence relaxation dynamics of artificially synthetic chlorosomes are studied by a sub 7 fs negative-time-delay laser spectroscopy at room temperature. The results provide direct evidence for the quantum coherence of the excitonic dephasing time of 23 +/- 1 fs at physiologically relevant temperatures, which is significant in the initial step of energy transfer in chlorosome or chlorosome-like photosynthetic systems. Meanwhile, coherent molecular vibrations in the excited state are also detected without the effect of wave-packet motion in the ground state, which shows that the excited state wave-packet motion contributes greatly to the vibrational modes of similar to 150 and similar to 1340 cm(-1) in artificial chlorosome systems. |
收录类别 | SCI |
资助信息 | 100 Talents Program of CAS; National Natural Science Foundation of China [61475169, 61521093, 11127901] |
WOS记录号 | WOS:000382766300011 |
内容类型 | 期刊论文 |
源URL | [http://ir.siom.ac.cn/handle/181231/27611] ![]() |
专题 | 上海光学精密机械研究所_强场激光物理国家重点实验室 |
作者单位 | 中国科学院上海光学精密机械研究所 |
推荐引用方式 GB/T 7714 | Han, Dongjia,Xue, Bing,Du, Juan,et al. Excitonic and vibrational coherence in artificial photosynthetic systems studied by negative-time ultrafast laser spectroscopy[J]. Phys. Chem. Chem. Phys.,2016,18(35):24252. |
APA | Han, Dongjia.,Xue, Bing.,Du, Juan.,Kobayashi, Takayoshi.,Miyatake, Tomohiro.,...&Leng, Yuxin.(2016).Excitonic and vibrational coherence in artificial photosynthetic systems studied by negative-time ultrafast laser spectroscopy.Phys. Chem. Chem. Phys.,18(35),24252. |
MLA | Han, Dongjia,et al."Excitonic and vibrational coherence in artificial photosynthetic systems studied by negative-time ultrafast laser spectroscopy".Phys. Chem. Chem. Phys. 18.35(2016):24252. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论