Electrochemical behavior of Nd3+ and Ho3+ in LiCl-KCl eutectic melt

	Electrochemical behavior of Nd3+ and Ho3+ in LiCl-KCl eutectic melt
	Zhao MS ; Lu XP ; Liang J
刊名	journal of rare earths
	1997
卷号	15 期号:2 页码:103-106
关键词	CHLORIDE
ISSN号	1002-0721
中文摘要	the electrochemical behavior of nd3+ and ho3+ ions on molybdenum electrode in the licl-kcl eutectic melts has been studied by cyclic voltammetry and open-circuit potentiometry. the results show that the reduction process of nd3+ and ho3+ ions on molybdenum electrode is one-step three electron reversible reaction. the diffusion coefficients of nd3+ and ho3+ ions are 1.13 x 10(-6) cm(2).s(-1)(450 degrees c) and 2.142 x 10(-5) cm(2).s(-1)(450 degrees c), respectively. the measured standard electrode potential of ho3+/ho is 2.987 v(vs. cl/cl-), being more negative than the theoretical one, the reason of which is also discussed.
收录类别	SCI收录期刊论文
语种	英语
公开日期	2010-12-22 ; 2011-06-09
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/24173]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Zhao MS,Lu XP,Liang J. Electrochemical behavior of Nd3+ and Ho3+ in LiCl-KCl eutectic melt[J]. journal of rare earths,1997,15(2):103-106.
APA	Zhao MS,Lu XP,&Liang J.(1997).Electrochemical behavior of Nd3+ and Ho3+ in LiCl-KCl eutectic melt.journal of rare earths,15(2),103-106.
MLA	Zhao MS,et al."Electrochemical behavior of Nd3+ and Ho3+ in LiCl-KCl eutectic melt".journal of rare earths 15.2(1997):103-106.