An electrochemical study of prussian blue microcrystallines mixed in PEO400 polymer electrolyte by solid-state voltammetry

	An electrochemical study of prussian blue microcrystallines mixed in PEO400 polymer electrolyte by solid-state voltammetry
	Guo LP ; Lin XQ
刊名	chemical research in chinese universities
	1997
卷号	13 期号:4 页码:304-311
关键词	CYCLIC VOLTAMMETRY FILMS GRAPHITE BEHAVIOR BATTERY DEVICE METAL
ISSN号	1005-9040
中文摘要	the electrochemistry of prussian blue mixed in a polymer medium containing mclo4 (m = li+, na+, k+, tba(+)) as the supporting electrolyte was studied by means of solid-state voltammetry. this approach is new in prussian blue studies. the behavior of pb in polymer electrolytes is somewhat similar to the well-known behavior for an electrochemically synthesized pb film in aqueous media. besides, k+, li+ and na+ ions can also transport through the crystal of pb because of its zeolitic nature. the transport of tba(+) ions is possible. kinetic control lies in the diffusion of cations in and out of the lattice of prussian blue. reduction waves of prussian blue depend on both the size and type of cations. pb is very stable upon electrochemical cycling in polymer electrolytes and air. this system may be used in rechargeable batteries and electrochromic devices.
收录类别	SCI收录期刊论文
语种	英语
公开日期	2010-12-22 ; 2011-06-09
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/23933]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Guo LP,Lin XQ. An electrochemical study of prussian blue microcrystallines mixed in PEO400 polymer electrolyte by solid-state voltammetry[J]. chemical research in chinese universities,1997,13(4):304-311.
APA	Guo LP,&Lin XQ.(1997).An electrochemical study of prussian blue microcrystallines mixed in PEO400 polymer electrolyte by solid-state voltammetry.chemical research in chinese universities,13(4),304-311.
MLA	Guo LP,et al."An electrochemical study of prussian blue microcrystallines mixed in PEO400 polymer electrolyte by solid-state voltammetry".chemical research in chinese universities 13.4(1997):304-311.