Ethylene polymerization with porous polystyrene spheres supported Cp2ZrCl2 catalyst
Qin YX ; Tang T ; Zhao ZF ; Huang BT
刊名journal of polymer science part a-polymer chemistry
2003
卷号41期号:21页码:3313-3319
关键词MOLECULAR-WEIGHT DISTRIBUTIONS CROSS-LINKED POLYSTYRENE METALLOCENE CATALYSTS RAC-PH2SI(IND)(2)ZRCL2 CATALYST PROPYLENE POLYMERIZATION OLEFIN POLYMERIZATION ZIRCONOCENE CATALYSTS ETHENE POLYMERIZATION PROPENE COPOLYMERIZATION
ISSN号0887-624x
通讯作者tang t
中文摘要a catalyst with porous polystyrene beads supported cp2zrcl2 was prepared and tested for ethylene polymerization with methylaluminoxane as a cocatalyst. by comparison, the porous supported catalyst maintained higher activity and produced polyethylene with better morphology than its corresponding solid supported catalyst. the differences between activities of the catalysts and morphologies of the products were reasonably explained by the fragmentation processes of support as frequently observed with the inorganic supported ziegler-natta catalysts. investigation into the distribution of polystyrene in the polyethylene revealed the fact that the porous polystyrene supported catalyst had undergone fragmentation during polymerization.
收录类别SCI
语种英语
WOS记录号WOS:000185967500012
公开日期2010-09-13
内容类型期刊论文
源URL[http://202.98.16.49/handle/322003/17617]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
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GB/T 7714
Qin YX,Tang T,Zhao ZF,et al. Ethylene polymerization with porous polystyrene spheres supported Cp2ZrCl2 catalyst[J]. journal of polymer science part a-polymer chemistry,2003,41(21):3313-3319.
APA Qin YX,Tang T,Zhao ZF,&Huang BT.(2003).Ethylene polymerization with porous polystyrene spheres supported Cp2ZrCl2 catalyst.journal of polymer science part a-polymer chemistry,41(21),3313-3319.
MLA Qin YX,et al."Ethylene polymerization with porous polystyrene spheres supported Cp2ZrCl2 catalyst".journal of polymer science part a-polymer chemistry 41.21(2003):3313-3319.
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