Synthesis and characterization of soluble poly(amideimide)s bearing triethylamine sulfonate groups as gas dehumidification membrane material
Chen G ; Zhang XS ; Wang JH ; Zhang SB
刊名journal of applied polymer science
2007
卷号106期号:5页码:3179-3184
关键词AROMATIC TETRACARBOXYLIC DIANHYDRIDES WATER-VAPOR PERMEATION BEHAVIOR RIGID-ROD POLYIMIDES POLYAMIDES POLY(AMIDE-IMIDE)S TRANSPORT DIAMINES AIR
ISSN号0021-8995
通讯作者zhang sb
中文摘要a series of soluble poly(amide-imide)s (pais) bearing triethylammonium sulfonate groups were synthesized directly using trimellitic anhydride chloride (tmac) polycondensation with sulfonated diamine such as 2,2'-benzidinedisulfonic acid (bdsa), 4,4'-diaminodiphenyl ether-2,2'-disulfonic acid (odads), and nonsulfonated diamine 4,4-diaminodiphenyl methane in the presence of triethylamine. the resulting copolymers exhibited high molecular weights (high inherent viscosity), and a combination of desirable properties such as good solubility in dipolar aprotic solvents, film-forming capability, and good mechanical properties. wide-angle x-ray diffraction revealed that the polymers were amorphous. these copolymers showed high permeability coefficients of water vapor because of the presence of the hydrophilic triethylammonium sulfonate groups. the water vapor permeability coefficients (p-w) and permselectivity coefficients of water vapor to nitrogen and methane [alpha(h2o/n-2) and (alpha(h2o/ch4)] of the films increased with increasing the amount of the triethylammonium sulfonated groups.
收录类别SCI
语种英语
WOS记录号WOS:000250410500043
公开日期2010-07-13
内容类型期刊论文
源URL[http://ir.ciac.jl.cn/handle/322003/13847]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
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GB/T 7714
Chen G,Zhang XS,Wang JH,et al. Synthesis and characterization of soluble poly(amideimide)s bearing triethylamine sulfonate groups as gas dehumidification membrane material[J]. journal of applied polymer science,2007,106(5):3179-3184.
APA Chen G,Zhang XS,Wang JH,&Zhang SB.(2007).Synthesis and characterization of soluble poly(amideimide)s bearing triethylamine sulfonate groups as gas dehumidification membrane material.journal of applied polymer science,106(5),3179-3184.
MLA Chen G,et al."Synthesis and characterization of soluble poly(amideimide)s bearing triethylamine sulfonate groups as gas dehumidification membrane material".journal of applied polymer science 106.5(2007):3179-3184.
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