Production of Bio-Based Gasoline by Noble-Metal-Catalyzed Hydrodeoxygenation of alpha-Angelica Lactone Derived Di/Trimers

CORC > 过程工程研究所 > 中国科学院过程工程研究所 > 多相复杂系统国家重点实验室

	Production of Bio-Based Gasoline by Noble-Metal-Catalyzed Hydrodeoxygenation of alpha-Angelica Lactone Derived Di/Trimers
	Ayodele, Olubunmi O.1,2,3; Dawodu, Folasegun A.2; Yan, Dongxia 1; Dong, Huixian 1; Xin, Jiayu 1; Zhang, Suojiang 1
刊名	CHEMISTRYSELECT
	2017-05-23
卷号	2 期号:15 页码:4219-4225
关键词	Angelica lactone biomass C-C coupling catalysts hydrodeoxygenation
ISSN号	2365-6549
英文摘要	Conversion of biomass into a suitable fuel involves series of chemical transformation including C-C coupling and hydrodeoxygenation reactions. Here, we have employed coupling reaction to a biomass-derived angelica lactone in the presence of mild alkaline catalysts, K2CO3 to obtain dimers and trimers in appropriate quantities. Hydrodeoxygenation of these molecules over carbon-supported noble metal catalysts was performed. Subsequently, the effect of operating parameters such as hydrogen pressure, temperature and reaction time on the hydrodeoxygenation of di/trimers were fully optimized and liquids suitable for gasoline application were obtained. This process has the potential of scale-up since the raw materials can easily be obtained from freely available biomass and the technology involved in carbon-carbon coupling and hydrodeoxygenation is well known.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	HIGH-QUALITY DIESEL ; TRANSPORTATION FUELS ; GAMMA-VALEROLACTONE ; CARBON-DIOXIDE ; BIOMASS ; LIQUID ; HYDROCARBONS ; CONVERSION ; HYDROGEN ; ALKANES
收录类别	SCI
语种	英语
WOS记录号	WOS:000402286000008
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/22658]
专题	过程工程研究所_多相复杂系统国家重点实验室
作者单位	1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 2.Univ Ibadan, Dept Ind Chem, Ibadan, Oyo State, Nigeria 3.Forestry Res Inst Nigeria, Dept Forest Prod Dev & Utilizat, Ibadan, Oyo State, Nigeria
推荐引用方式 GB/T 7714	Ayodele, Olubunmi O.,Dawodu, Folasegun A.,Yan, Dongxia,et al. Production of Bio-Based Gasoline by Noble-Metal-Catalyzed Hydrodeoxygenation of alpha-Angelica Lactone Derived Di/Trimers[J]. CHEMISTRYSELECT,2017,2(15):4219-4225.
APA	Ayodele, Olubunmi O.,Dawodu, Folasegun A.,Yan, Dongxia,Dong, Huixian,Xin, Jiayu,&Zhang, Suojiang.(2017).Production of Bio-Based Gasoline by Noble-Metal-Catalyzed Hydrodeoxygenation of alpha-Angelica Lactone Derived Di/Trimers.CHEMISTRYSELECT,2(15),4219-4225.
MLA	Ayodele, Olubunmi O.,et al."Production of Bio-Based Gasoline by Noble-Metal-Catalyzed Hydrodeoxygenation of alpha-Angelica Lactone Derived Di/Trimers".CHEMISTRYSELECT 2.15(2017):4219-4225.