Relationship of basicity and hydrogen bond properties of ionic liquids with its catalytic performance: Application to synthesis of propylene glycol methyl ether

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	Relationship of basicity and hydrogen bond properties of ionic liquids with its catalytic performance: Application to synthesis of propylene glycol methyl ether
	Chen, Shengxin 1,2; Liu, Ruixia 2; Li, Yajing 2,3; Zhang, Ruirui 2; Zhao, Cong 2; Tang, Hongguo 2; Qiao, Congzhen 1; Zhang, Suojiag 2
刊名	CATALYSIS COMMUNICATIONS
	2017-06-01
卷号	96 页码:69-73
关键词	Ionic liquids Hydrogen bond Basicity Propylene oxide Etherification Propylene glycol methyl ether
ISSN号	1566-7367
英文摘要	The relationship of basicity and hydrogen bond with catalytic performance was investigated in synthesis of propylene glycol methyl ether (PGME) catalyzed by various ILs ([Emim] [OAC], [Bmim] [OM], [N-2222] [OAC], [EtOH111 [OAC], [N-4444]Br, [Bmim] [N(CN)(2)], [Bmim]Br, [Bmim] [PF6]). The basicity and Kamlet-Taft parameters of each catalyst were evaluated by UV visible spectroscopy. It was found the catalytic performance is the synergistic effect of basicity and hydrogen bond donating ability in the synthesis of PGME from PO and CH3OH, which is quite different from the conventional basic catalytic mechanism.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Physical
研究领域[WOS]	Chemistry
关键词[WOS]	SOLVENT PROPERTIES ; SOLID BASE ; OXIDE ; METHANOL ; 1-METHOXY-2-PROPANOL
收录类别	SCI
语种	英语
WOS记录号	WOS:000401218700016
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/22543]
专题	过程工程研究所_多相复杂系统国家重点实验室
作者单位	1.Henan Univ, Coll Chem & Chem Engn, Kaifeng 475004, Peoples R China 2.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc, Inst Proc Engn,Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 3.Guangxi Univ, Coll Chem & Chem Engn, Nanning 530004, Peoples R China
推荐引用方式 GB/T 7714	Chen, Shengxin,Liu, Ruixia,Li, Yajing,et al. Relationship of basicity and hydrogen bond properties of ionic liquids with its catalytic performance: Application to synthesis of propylene glycol methyl ether[J]. CATALYSIS COMMUNICATIONS,2017,96:69-73.
APA	Chen, Shengxin.,Liu, Ruixia.,Li, Yajing.,Zhang, Ruirui.,Zhao, Cong.,...&Zhang, Suojiag.(2017).Relationship of basicity and hydrogen bond properties of ionic liquids with its catalytic performance: Application to synthesis of propylene glycol methyl ether.CATALYSIS COMMUNICATIONS,96,69-73.
MLA	Chen, Shengxin,et al."Relationship of basicity and hydrogen bond properties of ionic liquids with its catalytic performance: Application to synthesis of propylene glycol methyl ether".CATALYSIS COMMUNICATIONS 96(2017):69-73.