Synthesis, structure and optical properties of new organic-inorganic haloplumbates complexes (C5H10N3)PbX4 (X = Br, Cl), (C2H2N4)PbBr3

	Synthesis, structure and optical properties of new organic-inorganic haloplumbates complexes (C5H10N3)PbX4 (X = Br, Cl), (C2H2N4)PbBr3
	Li YY ; Lin CK ; Zheng GL ; Lin J
刊名	journal of solid state chemistry
	2007
卷号	180 期号:1 页码:173-179
关键词	LAYERED PEROVSKITE CRYSTAL-STRUCTURE SEMICONDUCTORS TRANSITIONS SPECTRA HALIDES SHEETS FILMS PB
ISSN号	0022-4596
通讯作者	lin j
中文摘要	layered organic-inorganic composite materials (c5h10n3)pbx4 (x = br 1, cl 2) containing histaminium dications were grown via a solution-cooling process, and their structure and optical properties were determined. the organic ligand-histaminium introduced into the corner-sharing octahedra of the 'pbx4- layer' contains both primary ammonium and imidazolium different from the traditionally primary amine found in this system. as comparison, another analogous amine of 3-amino-1,2,4-triazol was used as ligand to coordinate with pbbr2 in acid solution. a novel complex (c2h2n4)pbbr3 (3) was obtained with zigzag pbbr2 chains different from the pbx4 layer in compound as 1 and 2. the hybrid (c5h10n3)pbx4 show exciton absorption at 339 nm for x = cl and 419 nm for x = br with the corresponding emission at 360 and 436 nm, respectively. the different pbbr2 chain structure of compound 3 does not show photo luminescence.
收录类别	SCI
语种	英语
WOS记录号	WOS:000243951900024
公开日期	2010-07-13
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/13233]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Li YY,Lin CK,Zheng GL,et al. Synthesis, structure and optical properties of new organic-inorganic haloplumbates complexes (C5H10N3)PbX4 (X = Br, Cl), (C2H2N4)PbBr3[J]. journal of solid state chemistry,2007,180(1):173-179.
APA	Li YY,Lin CK,Zheng GL,&Lin J.(2007).Synthesis, structure and optical properties of new organic-inorganic haloplumbates complexes (C5H10N3)PbX4 (X = Br, Cl), (C2H2N4)PbBr3.journal of solid state chemistry,180(1),173-179.
MLA	Li YY,et al."Synthesis, structure and optical properties of new organic-inorganic haloplumbates complexes (C5H10N3)PbX4 (X = Br, Cl), (C2H2N4)PbBr3".journal of solid state chemistry 180.1(2007):173-179.