Four New Lanthanide-Nitronyl Nitroxide (Ln(III)=Pr-III, Sm-III, Eu-III, Tm-III) Complexes and a Tb-III Complex Exhibiting Single-Molecule Magnet Behavior

	Four New Lanthanide-Nitronyl Nitroxide (Ln(III)=Pr-III, Sm-III, Eu-III, Tm-III) Complexes and a Tb-III Complex Exhibiting Single-Molecule Magnet Behavior
	Xu JX ; Ma Y ; Liao DZ ; Xu GF ; Tang JK ; Wang C ; Zhou N ; Yan SP ; Cheng P ; Li LC
刊名	inorganic chemistry
	2009
卷号	48 期号:18 页码:8890-8896
关键词	COORDINATION POLYMERS CRYSTAL-STRUCTURE ORGANIC FRAMEWORKS FREE-RADICALS MAGNETIZATION LN DYNAMICS LIGAND SERIES GD
ISSN号	0020-1669
通讯作者	liao dz
中文摘要	five new complexes based on rare-earth-radical [ln(hfac)(3)(nit-5-br-3py)](2) (ln=pr (1), sm (2), eu (3), tb (4), tm (5); hfac = hexafluoroacetylacetonate; nit-5-br-3py = 2-(4,4,5,5-tetramethyl-3-oxylimidazoline-1-oxide)-5-bromo-3-pyridine) have been synthesized and characterized by x-ray crystal diffraction. the single-crystal structures show that these complexes have similar structures, in which a nit-5-br-3py molecule acts as a bridging ligand linking two ln(iii) ions through the oxygen atom of the n-o group and nitrogen atom from the pyridine ring to form a four-spin system. both static and dynamic magnetic properties were measured for complex 4, which exhibits single-molecule magnetism behavior.
收录类别	SCI
语种	英语
WOS记录号	WOS:000269671500032
公开日期	2010-06-18
内容类型	期刊论文
源URL	[http://202.98.16.49/handle/322003/12625]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Xu JX,Ma Y,Liao DZ,et al. Four New Lanthanide-Nitronyl Nitroxide (Ln(III)=Pr-III, Sm-III, Eu-III, Tm-III) Complexes and a Tb-III Complex Exhibiting Single-Molecule Magnet Behavior[J]. inorganic chemistry,2009,48(18):8890-8896.
APA	Xu JX.,Ma Y.,Liao DZ.,Xu GF.,Tang JK.,...&Li LC.(2009).Four New Lanthanide-Nitronyl Nitroxide (Ln(III)=Pr-III, Sm-III, Eu-III, Tm-III) Complexes and a Tb-III Complex Exhibiting Single-Molecule Magnet Behavior.inorganic chemistry,48(18),8890-8896.
MLA	Xu JX,et al."Four New Lanthanide-Nitronyl Nitroxide (Ln(III)=Pr-III, Sm-III, Eu-III, Tm-III) Complexes and a Tb-III Complex Exhibiting Single-Molecule Magnet Behavior".inorganic chemistry 48.18(2009):8890-8896.