Metal-free radical oxidative alkoxycarbonylation and imidation of alkanes | |
Lu, Lijun1; Cheng, Danyang1; Zhan, Yuanfeng1; Shi, Renyi1; Chiang, Chien-Wei1; Lei AW(雷爱文)1,2 | |
刊名 | Chemical Communications |
2017 | |
卷号 | 53期号:51页码:6852-6855 |
ISSN号 | 1359-7345 |
通讯作者 | 雷爱文 |
英文摘要 | A metal-free radical oxidative carbonylation of alkanes is demonstrated, yielding esters and imides by means of di-tert-butylperoxide as an oxidant. Various alkanes, alcohols and amides were compatible in this system generating the desired carbonyl products in up to 86% yields. We proposed a plausible radical cross-coupling process based on the preliminary mechanistic studies. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | the National Natural Science Foundation of China (21390402;21520102003);the Ministry of Science and Technology of China (2012YQ120060);the Fundamental Research Funds for the Central Universities and the Program of Introducing Talents of Discipline to Universities of China (111 Program) |
语种 | 英语 |
WOS记录号 | WOS:000404282900010 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/22043] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
作者单位 | 1.Wuhan Univ, Inst Adv Studies, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Lu, Lijun,Cheng, Danyang,Zhan, Yuanfeng,et al. Metal-free radical oxidative alkoxycarbonylation and imidation of alkanes[J]. Chemical Communications,2017,53(51):6852-6855. |
APA | Lu, Lijun,Cheng, Danyang,Zhan, Yuanfeng,Shi, Renyi,Chiang, Chien-Wei,&Lei AW.(2017).Metal-free radical oxidative alkoxycarbonylation and imidation of alkanes.Chemical Communications,53(51),6852-6855. |
MLA | Lu, Lijun,et al."Metal-free radical oxidative alkoxycarbonylation and imidation of alkanes".Chemical Communications 53.51(2017):6852-6855. |
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