Metal-free radical oxidative alkoxycarbonylation and imidation of alkanes
Lu, Lijun1; Cheng, Danyang1; Zhan, Yuanfeng1; Shi, Renyi1; Chiang, Chien-Wei1; Lei AW(雷爱文)1,2
刊名Chemical Communications
2017
卷号53期号:51页码:6852-6855
ISSN号1359-7345
通讯作者雷爱文
英文摘要

A metal-free radical oxidative carbonylation of alkanes is demonstrated, yielding esters and imides by means of di-tert-butylperoxide as an oxidant. Various alkanes, alcohols and amides were compatible in this system generating the desired carbonyl products in up to 86% yields. We proposed a plausible radical cross-coupling process based on the preliminary mechanistic studies.

学科主题物理化学与绿色催化
收录类别SCI
资助信息the National Natural Science Foundation of China (21390402;21520102003);the Ministry of Science and Technology of China (2012YQ120060);the Fundamental Research Funds for the Central Universities and the Program of Introducing Talents of Discipline to Universities of China (111 Program)
语种英语
WOS记录号WOS:000404282900010
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/22043]  
专题兰州化学物理研究所_OSSO国家重点实验室
作者单位1.Wuhan Univ, Inst Adv Studies, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714
Lu, Lijun,Cheng, Danyang,Zhan, Yuanfeng,et al. Metal-free radical oxidative alkoxycarbonylation and imidation of alkanes[J]. Chemical Communications,2017,53(51):6852-6855.
APA Lu, Lijun,Cheng, Danyang,Zhan, Yuanfeng,Shi, Renyi,Chiang, Chien-Wei,&Lei AW.(2017).Metal-free radical oxidative alkoxycarbonylation and imidation of alkanes.Chemical Communications,53(51),6852-6855.
MLA Lu, Lijun,et al."Metal-free radical oxidative alkoxycarbonylation and imidation of alkanes".Chemical Communications 53.51(2017):6852-6855.
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