Syntheses and reactions of N-Perfluoroalkanesulfonylimino sulfurous dichlorides

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	Syntheses and reactions of N-Perfluoroalkanesulfonylimino sulfurous dichlorides
	Xu B(许斌) ; Xu GL(许国林) ; Qin CY(钦朝岳) ; Xu Y(许勇) ; Chu QL(储千里) ; Zhu SZ(朱仕正)
刊名	Heteroatom Chem.
	1999
卷号	10 期号:1 页码:41-48
ISSN号	1042-7163
其他题名	RfSO=2N=SCl=2 的合成及其反应研究
英文摘要	Treatment of N,N-dichloroperfluoroalkanesulfonylamines with sulfur powder at room temperature gave the title products R=1SO=2N=SCl=2 in good yields. They reacted readily with dimethyl sulfoxide, chloral, DMF, benzophenone, and similar compounds to form to corresponding imines R=1SO=2N-YR^1R^2(Y:S,C). A reaction mechanism, one involving formation of a four-membered intermediate, is proposed.
学科主题	有机氟化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/(SICI)1098-1071(1999)10:1<41::AID-HC8>3.0.CO;2-Y
语种	英语
WOS记录号	WOS:000078409400008
公开日期	2013-01-18
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/14208]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
推荐引用方式 GB/T 7714	Xu B,Xu GL,Qin CY,et al. Syntheses and reactions of N-Perfluoroalkanesulfonylimino sulfurous dichlorides[J]. Heteroatom Chem.,1999,10(1):41-48.
APA	许斌,许国林,钦朝岳,许勇,储千里,&朱仕正.(1999).Syntheses and reactions of N-Perfluoroalkanesulfonylimino sulfurous dichlorides.Heteroatom Chem.,10(1),41-48.
MLA	许斌,et al."Syntheses and reactions of N-Perfluoroalkanesulfonylimino sulfurous dichlorides".Heteroatom Chem. 10.1(1999):41-48.