New rare earth metal bis(alkyl)s bearing an iminophosphonamido ligand. Synthesis and catalysis toward highly 3,4-selective polymerization of isoprene

	New rare earth metal bis(alkyl)s bearing an iminophosphonamido ligand. Synthesis and catalysis toward highly 3,4-selective polymerization of isoprene
	Li SH ; Miao W ; Tang T ; Dong WM ; Zhang XQ ; Cui DM
刊名	organometallics
	2008
卷号	27 期号:4 页码:718-725
关键词	LANTHANIDE ALKYL COMPLEXES STEREOSPECIFIC POLYMERIZATION 1 DIENE POLYMERIZATION METHYL-METHACRYLATE BUTADIENE REACTIVITY COPOLYMERIZATION ETHYLENE NEODYMIUM 3-DIENE POLYMERIZATION
ISSN号	0276-7333
通讯作者	cui dm
中文摘要	newrareearth metal bis(alkyl) complexes [(npnph)ln(ch2sime3)(2)(thf) (npnph:n(ph)pph2=nc6h2me3-2,4,6; ln = sc (3a), ln = y (3b), ln = lu (3c)) and [(npnpy)sc(ch2sime3)(2)(thf)1 (npnpy = n(py)pph2=nc6h2me3-2,4,6) (3d)) have been prepared via protonolysis reaction between rare earth metal tris(alkyl)s and the corresponding iminophosphonamines. complexes 3a-d are analogous monomers of thf solvate. each metal ion coordinates to a eta(2)-chelated npn ligand and two cis-located alkyl groups, adopting tetrahedron geometry.
收录类别	SCI
语种	英语
WOS记录号	WOS:000253268000032
公开日期	2010-04-14
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/10565]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Li SH,Miao W,Tang T,et al. New rare earth metal bis(alkyl)s bearing an iminophosphonamido ligand. Synthesis and catalysis toward highly 3,4-selective polymerization of isoprene[J]. organometallics,2008,27(4):718-725.
APA	Li SH,Miao W,Tang T,Dong WM,Zhang XQ,&Cui DM.(2008).New rare earth metal bis(alkyl)s bearing an iminophosphonamido ligand. Synthesis and catalysis toward highly 3,4-selective polymerization of isoprene.organometallics,27(4),718-725.
MLA	Li SH,et al."New rare earth metal bis(alkyl)s bearing an iminophosphonamido ligand. Synthesis and catalysis toward highly 3,4-selective polymerization of isoprene".organometallics 27.4(2008):718-725.