Asymmetric Catalysis with Chiral Ferrocene Ligands

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	Asymmetric Catalysis with Chiral Ferrocene Ligands
	Dai LX(戴立信) ; Tu T(涂涛) ; You SL(游书力) ; Deng WP(邓卫平) ; Hou XL(侯雪龙)
刊名	Accounts Chem. Res.
	2003
卷号	36 期号:9 页码:659-667
ISSN号	0001-4842
其他题名	手性二茂铁为配体的不对称催化
通讯作者	侯雪龙
英文摘要	Chiral ferrocene ligands have been widely used in asymmetric catalysis. The advantages of using ferrocene as a scaffold for chiral ligands are described, particularly those regarding planar chirality, rigid bulkiness, and ease of derivatization. The role of planar chirality in 1,2- and 1,1￠-disubstituted ferrocene systems is discussed. By using a bulky ferrocene fragment, novel ferrocene ligands were designed, and high enantioselectivity and regioselectivity were achieved in the allylic substitution reaction of monosubstituted allyl substrates. Using the tunable electronic properties of a diphosphine-oxazoline ferrocenyl ligand, the regioselectivity of the intermolecular asymmetric Heck reaction was also examined.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/ar020153m
语种	英语
WOS记录号	WOS:000185430400003
公开日期	2013-02-19
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/15885]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Dai LX,Tu T,You SL,et al. Asymmetric Catalysis with Chiral Ferrocene Ligands[J]. Accounts Chem. Res.,2003,36(9):659-667.
APA	戴立信,涂涛,游书力,邓卫平,&侯雪龙.(2003).Asymmetric Catalysis with Chiral Ferrocene Ligands.Accounts Chem. Res.,36(9),659-667.
MLA	戴立信,et al."Asymmetric Catalysis with Chiral Ferrocene Ligands".Accounts Chem. Res. 36.9(2003):659-667.