Palladium(II)-Catalyzed Synthesis of Functionalized Indenes from o-Alkynylbenzylidene Ketones

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	Palladium(II)-Catalyzed Synthesis of Functionalized Indenes from o-Alkynylbenzylidene Ketones
	Zhou F(周峰) ; Han XL(韩秀玲) ; Lu XY(陆熙炎)
刊名	J. Org. Chem.
	2011
卷号	76 期号:5 页码:1491-1494
ISSN号	0022-3263
其他题名	两价钯催化下从邻炔基苯亚甲基酮合成官能团化茚
通讯作者	陆熙炎
英文摘要	An efficient method for the synthesis of functionalized indenes from o-alkynylbenzylidene ketones under palladium(II) catalysis was developed. The reaction is initiated by trans-nucleopalladation of alkynes, followed by conjugate addition and quenched by protonolysis of the carbon palladium bond. With acetate and halide ions as nucleophiles, 3-acetoxy- and 3-halogen-substituted indenes could be obtained in high yields.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/jo1023574
语种	英语
WOS记录号	WOS:000287636200038
公开日期	2013-01-22
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/14902]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Zhou F,Han XL,Lu XY. Palladium(II)-Catalyzed Synthesis of Functionalized Indenes from o-Alkynylbenzylidene Ketones[J]. J. Org. Chem.,2011,76(5):1491-1494.
APA	周峰,韩秀玲,&陆熙炎.(2011).Palladium(II)-Catalyzed Synthesis of Functionalized Indenes from o-Alkynylbenzylidene Ketones.J. Org. Chem.,76(5),1491-1494.
MLA	周峰,et al."Palladium(II)-Catalyzed Synthesis of Functionalized Indenes from o-Alkynylbenzylidene Ketones".J. Org. Chem. 76.5(2011):1491-1494.