Highly enantioselective hydrogenation of exocyclic double bond of N-tosyloxazolidinones catalyzed by a neutral rhodium complex and its synthetic applications N-tosyloxazolidinones; rhodium complex

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	Highly enantioselective hydrogenation of exocyclic double bond of N-tosyloxazolidinones catalyzed by a neutral rhodium complex and its synthetic applications N-tosyloxazolidinones; rhodium complex
	Shen ZM(沈增明) ; Lu XY(陆熙炎) ; Lei AW(雷爱文)
刊名	Tetrahedron
	2006
卷号	62 期号:39 页码:9237-9246
ISSN号	0040-4020
其他题名	一个中性铑络合物催化的N-对甲苯磺酰基噁唑啉环外双键的高选择性氢化反应及其在合成中的应用
通讯作者	陆熙炎
英文摘要	A highly enantioselective synthesis of optically active N-tosyl-4-alkyl-1,3-oxazolidin-2-ones based on the asymmetric hydrogenation of the trisubstituted exocyclic double bond of N-tosyl-4-alkylidene-1,3-oxazolidin-2-ones under the catalysis of neutral [Rh(COD)Cl]2 (COD= 1,5-cyclooctadiene) and (S)-(+)-DTBM-SEGPHOS was developed. The utility of this highly enantioselective reaction was exemplified by the synthesis of optically active amino acids, amino alcohols, and piperidine derivatives. (c) 2006 Elsevier Ltd. All rights reserved.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1016/j.tet.2006.07.024
语种	英语
公开日期	2013-01-22
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/14844]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Shen ZM,Lu XY,Lei AW. Highly enantioselective hydrogenation of exocyclic double bond of N-tosyloxazolidinones catalyzed by a neutral rhodium complex and its synthetic applications N-tosyloxazolidinones; rhodium complex[J]. Tetrahedron,2006,62(39):9237-9246.
APA	沈增明,陆熙炎,&雷爱文.(2006).Highly enantioselective hydrogenation of exocyclic double bond of N-tosyloxazolidinones catalyzed by a neutral rhodium complex and its synthetic applications N-tosyloxazolidinones; rhodium complex.Tetrahedron,62(39),9237-9246.
MLA	沈增明,et al."Highly enantioselective hydrogenation of exocyclic double bond of N-tosyloxazolidinones catalyzed by a neutral rhodium complex and its synthetic applications N-tosyloxazolidinones; rhodium complex".Tetrahedron 62.39(2006):9237-9246.