Effect of halide ligands on the reactivity of carbon-palladium bonds: Implications for desigining catalytic reactions

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	Effect of halide ligands on the reactivity of carbon-palladium bonds: Implications for desigining catalytic reactions
	Wang Z(王忠) ; Zhang ZG(张兆国) ; Lu XY(陆熙炎)
刊名	Organometallics
	2000
卷号	19 期号:5 页码:775-780
ISSN号	0276-7333
其他题名	卤离子配体对碳-钯键反应性的影响：有关催化反应的设计
通讯作者	陆熙炎
英文摘要	The integral role of halide ions as a ligand in divalent palladium-catalyzed nucleophilealkyne-α，β-unsaturated carbonyl coupling reaction as well as in the stoichiometric reaction of arylpalladium reagents with acrolein was studied. Excess of halide ions can effectively inhibit theβ-hydride elimination of a (2-oxoalkyl)palladium intermediate, giving preferentially the protonolysis product in acidic media. This result may have further implications for the design and development of divalent palladium-catalyzed reactions
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/om990670h
语种	英语
公开日期	2013-01-22
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/14768]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Wang Z,Zhang ZG,Lu XY. Effect of halide ligands on the reactivity of carbon-palladium bonds: Implications for desigining catalytic reactions[J]. Organometallics,2000,19(5):775-780.
APA	王忠,张兆国,&陆熙炎.(2000).Effect of halide ligands on the reactivity of carbon-palladium bonds: Implications for desigining catalytic reactions.Organometallics,19(5),775-780.
MLA	王忠,et al."Effect of halide ligands on the reactivity of carbon-palladium bonds: Implications for desigining catalytic reactions".Organometallics 19.5(2000):775-780.