Synthesis of (+) or (-)-2-(8'-Diphenylphosphino-1'-naphthyl) oxazoline ligands and their application in Pd-catalyzed allylic alkylation reaction | |
Ma SM(麻生明) ; Duan DH(段德慧) | |
刊名 | Chin. J. Chem. |
2002 | |
卷号 | 20期号:11页码:1363-1368 |
ISSN号 | 1001-604X |
其他题名 | (+)or (-)-2-(8'1二苯基膦基萘-1'-)噁唑啉合成及在钯催化烯丙基烷基化反应中的应用 |
通讯作者 | 麻生明 |
英文摘要 | We synthesized optically active 2-(8'-diphenylphosphino-1'-naphthyl) oxazoline ligands by palladium-catalyzed coupling reactions of (trimethylsilyl) diphenylphosphine with 2-(8'-bromo1'-naphthyl)oxazolines, which, in turn, were prepared from 8-bromo-1-naphthoyl chloride by the reaction with natural optical active amino aleohols. Pd-catalyzed allylic alkylation reaction induced by these chiral ligands gave the allylic substiuted products in high yields and moderate ee values. |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1002/cjoc.20020201135 |
语种 | 英语 |
公开日期 | 2013-01-15 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/11896] |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Ma SM,Duan DH. Synthesis of (+) or (-)-2-(8'-Diphenylphosphino-1'-naphthyl) oxazoline ligands and their application in Pd-catalyzed allylic alkylation reaction[J]. Chin. J. Chem.,2002,20(11):1363-1368. |
APA | 麻生明,&段德慧.(2002).Synthesis of (+) or (-)-2-(8'-Diphenylphosphino-1'-naphthyl) oxazoline ligands and their application in Pd-catalyzed allylic alkylation reaction.Chin. J. Chem.,20(11),1363-1368. |
MLA | 麻生明,et al."Synthesis of (+) or (-)-2-(8'-Diphenylphosphino-1'-naphthyl) oxazoline ligands and their application in Pd-catalyzed allylic alkylation reaction".Chin. J. Chem. 20.11(2002):1363-1368. |
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