Palladium(0)-Catalyzed Reaction of Cyclopropylidenecycloalkanes with Carbon Dioxide

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	Palladium(0)-Catalyzed Reaction of Cyclopropylidenecycloalkanes with Carbon Dioxide
	Chen K(陈凯) ; Jiang M(蒋敏) ; Zhang Z(张震) ; Wei Y(魏音) ; Shi M(施敏)
刊名	Eur. J. Org. Chem.
	2011
期号	35 页码:7189-7193
ISSN号	1434-193X
其他题名	金属钯(0)催化的环烷基亚甲基环丙烷和CO2的反应研究
英文摘要	Cyclopropylidenecycloalkanes, which are highly strained methylenecyclopropane (MCPs) containing a cycloalkane moiety, react with carbon dioxide smoothly to give the corresponding five-membered lactone derivatives in moderate to good yields through a cyclopropane ring-opening process in the presence of Pd0 catalyst and PCy3 upon heating under 40 atm of CO2. The relative configuration of the major diastereomers has been determined and a plausible reaction mechanism has also been proposed.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/ejoc.201101192
语种	英语
WOS记录号	WOS:000297466000020
公开日期	2013-01-09
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/10440]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Chen K,Jiang M,Zhang Z,et al. Palladium(0)-Catalyzed Reaction of Cyclopropylidenecycloalkanes with Carbon Dioxide[J]. Eur. J. Org. Chem.,2011(35):7189-7193.
APA	陈凯,蒋敏,张震,魏音,&施敏.(2011).Palladium(0)-Catalyzed Reaction of Cyclopropylidenecycloalkanes with Carbon Dioxide.Eur. J. Org. Chem.(35),7189-7193.
MLA	陈凯,et al."Palladium(0)-Catalyzed Reaction of Cyclopropylidenecycloalkanes with Carbon Dioxide".Eur. J. Org. Chem. .35(2011):7189-7193.