Asymmetric catalysis of Morita-Baylis-Hillman reactions by chiral phosphine Lewis bases beating multiple phenol groups | |
Shi M(施敏) ; Chen LH(陈连辉) ; Liu YH(刘英豪) | |
刊名 | Chirality |
2007 | |
卷号 | 19期号:2页码:124-128 |
其他题名 | 含有多酚羟基手性膦化合物催化的不对称Baylis-Hillman反应 |
通讯作者 | 施敏 |
英文摘要 | In the Morita-Baylis-Hillman (MBH) reactions of arylaldehydes with methyl vinyl ketone, it was observed that in the presence of a catalytic amount of a chiral phosphine Lewis base (CPLB) beating multiple phenol groups, such as CPLB1 (10 mol %), the corresponding MBH adducts could be obtained in moderate to good yields with low to moderate ee's (4-45% ee) at ambient temperature (10 degrees C) in THF. |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1002/chir.20313 |
语种 | 英语 |
WOS记录号 | WOS:000243499400006 |
公开日期 | 2013-01-09 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/10124] |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Shi M,Chen LH,Liu YH. Asymmetric catalysis of Morita-Baylis-Hillman reactions by chiral phosphine Lewis bases beating multiple phenol groups[J]. Chirality,2007,19(2):124-128. |
APA | Shi M,Chen LH,&Liu YH.(2007).Asymmetric catalysis of Morita-Baylis-Hillman reactions by chiral phosphine Lewis bases beating multiple phenol groups.Chirality,19(2),124-128. |
MLA | Shi M,et al."Asymmetric catalysis of Morita-Baylis-Hillman reactions by chiral phosphine Lewis bases beating multiple phenol groups".Chirality 19.2(2007):124-128. |
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