Asymmetric catalysis of Morita-Baylis-Hillman reactions by chiral phosphine Lewis bases beating multiple phenol groups
Shi M(施敏) ; Chen LH(陈连辉) ; Liu YH(刘英豪)
刊名Chirality
2007
卷号19期号:2页码:124-128
其他题名含有多酚羟基手性膦化合物催化的不对称Baylis-Hillman反应
通讯作者施敏
英文摘要In the Morita-Baylis-Hillman (MBH) reactions of arylaldehydes with methyl vinyl ketone, it was observed that in the presence of a catalytic amount of a chiral phosphine Lewis base (CPLB) beating multiple phenol groups, such as CPLB1 (10 mol %), the corresponding MBH adducts could be obtained in moderate to good yields with low to moderate ee's (4-45% ee) at ambient temperature (10 degrees C) in THF.
学科主题金属有机化学
收录类别SCI
原文出处http://dx.doi.org/10.1002/chir.20313
语种英语
WOS记录号WOS:000243499400006
公开日期2013-01-09
内容类型期刊论文
源URL[http://202.127.28.38/handle/331003/10124]  
专题上海有机化学研究所_金属有机化学国家重点实验室
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Shi M,Chen LH,Liu YH. Asymmetric catalysis of Morita-Baylis-Hillman reactions by chiral phosphine Lewis bases beating multiple phenol groups[J]. Chirality,2007,19(2):124-128.
APA Shi M,Chen LH,&Liu YH.(2007).Asymmetric catalysis of Morita-Baylis-Hillman reactions by chiral phosphine Lewis bases beating multiple phenol groups.Chirality,19(2),124-128.
MLA Shi M,et al."Asymmetric catalysis of Morita-Baylis-Hillman reactions by chiral phosphine Lewis bases beating multiple phenol groups".Chirality 19.2(2007):124-128.
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