Chemical fixation of carbon dioxide co-catalyzed by a combination of Schiff bases or phenols and organic bases

CORC > 上海有机化学研究所 > 中国科学院上海有机化学研究所 > 金属有机化学国家重点实验室

	Chemical fixation of carbon dioxide co-catalyzed by a combination of Schiff bases or phenols and organic bases
	Shen YM(沈玉梅) ; Duan WL(段伟良) ; Shi M(施敏)
刊名	Eur. J. Org. Chem.
	2004
期号	14 页码:3080-3089
其他题名	席夫碱和苯酚以及有机碱共催化的CO2固定反应研究
通讯作者	施敏
英文摘要	Binaphthyldiamino, ethyldiamino and cyclohexyldiamino Schiff bases can catalyze the reaction of epoxides with carbon dioxide in the presence of catalytic amounts of various organic bases to give the corresponding cyclic carbonates in high yields. The simplest binaphthyldiamino Schiff base, derived from the reaction of binaphthyldiamine with salicylaldehyde, gave the highest yield of cyclic carbonate. This catalytic system can be further simplified by use of a phenol instead of the Schiff base to give the corresponding cyclic carbonates in high yields as well. Mechanistic insights were obtained based on a deuterium labeling experiment. The reaction of aziridines with CO2 and epoxide with CS2 were also examined under the same reaction conditions. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/ejoc.200400083
语种	英语
WOS记录号	WOS:000222894900015
公开日期	2013-01-09
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/9914]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Shen YM,Duan WL,Shi M. Chemical fixation of carbon dioxide co-catalyzed by a combination of Schiff bases or phenols and organic bases[J]. Eur. J. Org. Chem.,2004(14):3080-3089.
APA	Shen YM,Duan WL,&Shi M.(2004).Chemical fixation of carbon dioxide co-catalyzed by a combination of Schiff bases or phenols and organic bases.Eur. J. Org. Chem.(14),3080-3089.
MLA	Shen YM,et al."Chemical fixation of carbon dioxide co-catalyzed by a combination of Schiff bases or phenols and organic bases".Eur. J. Org. Chem. .14(2004):3080-3089.