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	A new asymmetric synthesis of (R)-3-methylpyrrolidine alkaloids starting from (S)-malic acid
	Huang,PQ ; Ruan,YP ; Zheng,X ; Chan,WH ; Lee,AWM ; Zheng X(郑啸)
	2001-08-01
关键词	ANTS LEPTOTHORACINI POISON GLANDS PYRROLIDINES ANALOGS
英文摘要	Diastereoselective methylation of dimethyl (S)-malate (8) followed by two three-step reductive dehydroxylation procedures afforded dimethyl (R)-2-methylsuccinate (16) in 80.2% and 84.7% ee respectively, the later was further transformed into the natural enantiomers of ant venom alkaloids (R)-leptothoracine (1) and (R)-3-methyl-N-(2-phenylethyl)pyrrolidine (2) and (3R, 2'S)-3-methyl-N-(2-methylbutyl)pyrrolidine (3).
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/71501]
专题	医学院－已发表论文
推荐引用方式 GB/T 7714	Huang,PQ,Ruan,YP,Zheng,X,et al. A new asymmetric synthesis of (R)-3-methylpyrrolidine alkaloids starting from (S)-malic acid[J],2001.
APA	Huang,PQ,Ruan,YP,Zheng,X,Chan,WH,Lee,AWM,&郑啸.(2001).A new asymmetric synthesis of (R)-3-methylpyrrolidine alkaloids starting from (S)-malic acid..
MLA	Huang,PQ,et al."A new asymmetric synthesis of (R)-3-methylpyrrolidine alkaloids starting from (S)-malic acid".(2001).

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