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	萜烯酚树脂性能研究; STUDIES ON THE PROPERTIES of TERPENE-PHENOLIC RESIN
	袁友珠 ; 程芝
	1994
关键词	萜烯 苯酚 萜烯酚树脂 Terpene-phenolic resin Terpene Phenol
英文摘要	由中国脂松节油和苯酚共缩聚得到的萜烯酚树脂的性能、结构。实验结果指出，萜烯酚树脂的密度碘值（I%）18%~20%，酚羟基值（OH%1.3%。软化点100.0~135.0℃的萜烯酚树脂，VPO测定的分子量为600~630。不同软化点树脂在稀浓度下表现等同的溶液粘度，较高浓度时，软化点高溶液粘度较大。根据对萜烯酚树脂性能和Ir的研究结果，讨论了树脂的可能形成机理。; t was Found that the terpene-phenolic resins prepared by Friedel-CraFt' s reaction of turpentineFrom Pinus massoniana with phenol possess 18%～20%iodine numbers(l numbers,I%)and 1.3%hydroxyl numbers(OH%).Molecular weights of the resins with softening point of 100.0～135.0℃are in the range of 600～630 according to VPO results.Viscosity of the resins in toluene varies in concen-trated solution with their softening points (high softening point terpene-phenolic resin with high viscosity)although the same viscosity was tested in dilute solutions.Para-substituted benzyl group are the mainstructure in the resins From IR spectroscopic data at v 850 cm￣(-1).The presence of twin-methyl groups at v1380～1365 em￣(-1) and aryl oxides 1270～1110 cm￣(-1) in the resin was also evidenced by the IR spectra,Thepossible reaction pathway in the resin Formation has been discussed.
语种	zh_CN
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/107718]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	袁友珠,程芝. 萜烯酚树脂性能研究, STUDIES ON THE PROPERTIES of TERPENE-PHENOLIC RESIN[J],1994.
APA	袁友珠,&程芝.(1994).萜烯酚树脂性能研究..
MLA	袁友珠,et al."萜烯酚树脂性能研究".(1994).

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