Gold-catalyzed intermolecular oxidation of chiral homopropargyl sulfonamides: a reliable access to enantioenriched pyrrolidin-3-ones

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	Gold-catalyzed intermolecular oxidation of chiral homopropargyl sulfonamides: a reliable access to enantioenriched pyrrolidin-3-ones
	Shu, Chao ; Li, Long ; Yu, Yong-Fei ; Jiang, Shuang ; Ye, Long-Wu ; Ye LW(叶龙武)
刊名	http://dx.doi.org/10.1039/c3cc49238a
	2014
关键词	ASYMMETRIC-SYNTHESIS EFFICIENT SYNTHESIS PROPARGYLIC ALCOHOLS TROPANE ALKALOIDS CYCLIZATION REARRANGEMENT DERIVATIVES ALKYNES CARBENES LIGANDS
英文摘要	National Natural Science Foundation of China [21102119, 21272191]; NFFTBS [J1310024]; PCSIRT; A gold-catalyzed intermolecular oxidation of chiral homopropargyl sulfonamides has been developed, which provides a reliable access to synthetically useful chiral pyrrolidin-3-ones with excellent ee, by combining the chiral tert-butylsulfinimine chemistry and gold catalysis. This methodology has also been used in the facile synthesis of natural product (-)-irniine. The use of readily available starting materials, a broad substrate scope, a simple procedure and the mild nature of this reaction render it a viable alternative for the synthesis of enantioenriched pyrrolidin-3-ones.
语种	英语
出版者	ROYAL SOC CHEMISTRY
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/89476]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Shu, Chao,Li, Long,Yu, Yong-Fei,et al. Gold-catalyzed intermolecular oxidation of chiral homopropargyl sulfonamides: a reliable access to enantioenriched pyrrolidin-3-ones[J]. http://dx.doi.org/10.1039/c3cc49238a,2014.
APA	Shu, Chao,Li, Long,Yu, Yong-Fei,Jiang, Shuang,Ye, Long-Wu,&叶龙武.(2014).Gold-catalyzed intermolecular oxidation of chiral homopropargyl sulfonamides: a reliable access to enantioenriched pyrrolidin-3-ones.http://dx.doi.org/10.1039/c3cc49238a.
MLA	Shu, Chao,et al."Gold-catalyzed intermolecular oxidation of chiral homopropargyl sulfonamides: a reliable access to enantioenriched pyrrolidin-3-ones".http://dx.doi.org/10.1039/c3cc49238a (2014).