Theoretical modeling coupled with experimental study on the preparation and characterization comparison of fluorinated copolymers: Effect of chain structure on copolymer properties

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	Theoretical modeling coupled with experimental study on the preparation and characterization comparison of fluorinated copolymers: Effect of chain structure on copolymer properties
	Zhou, Yin-Ning ; Luo, Zheng-Hong ; Chen, Jian-Hua ; Luo ZH(罗正鸿)
刊名	http://dx.doi.org/10.1002/aic.14057
	2013
关键词	TRANSFER RADICAL POLYMERIZATION GLASS-TRANSITION TEMPERATURE LOW SURFACE-ENERGY GRADIENT COPOLYMERS BLOCK-COPOLYMERS TRIBLOCK COPOLYMERS 2-HYDROXYETHYL METHACRYLATE SEQUENCE DISTRIBUTION DIBLOCK COPOLYMERS PHASE-BEHAVIOR
英文摘要	National Ministry of Science and Technology of China [2012CB21500402]; National Natural Science Foundation of China [21076171, 21276213]; State-Key Laboratory of Chemical Engineering of Tsinghua University [SKL-ChE-10A03]; Theoretical modeling coupled with an experimental study is presented for the preparation and characterization comparison of the amphiphilic copolymers of 2, 2, 3, 3, 4, 4, 4-heptafluorobutyl methacrylate (HFBMA) and 2-hydroxyethyl methacrylate (HEMA) to achieve a multiscale generalization of the polymeric system. A series of amphiphilic copolymers having different chain structures with HFBMA as the hydrophobic component and HEMA as the hydrophilic component was first synthesized through atom transfer radical copolymerization (ATRcoP) or model-based semibatch ATRcoP. Theoretical modeling is used to optimize the macromolecular structure and experimental approaches that are used to prepare copolymers of HFBMA and HEMA with some tailor-made polymer properties. Furthermore, a systematic comparison of major properties (i.e., thermal, micellization, and surface properties) of these fluorinated copolymers (i.e., random, block, linear gradient, and inverse linear gradient copolymers) was carried out. The results show that these fluorinated copolymers with different chain structures have dissimilar properties. The results also demonstrate that the approach of coupling theoretical modeling with an experimental study can be used to guide a multiscale generalization of the polymeric system for practical application. (c) 2013 American Institute of Chemical Engineers AIChE J, 59: 3019-3033, 2013
语种	英语
出版者	WILEY-BLACKWELL
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/88957]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Zhou, Yin-Ning,Luo, Zheng-Hong,Chen, Jian-Hua,et al. Theoretical modeling coupled with experimental study on the preparation and characterization comparison of fluorinated copolymers: Effect of chain structure on copolymer properties[J]. http://dx.doi.org/10.1002/aic.14057,2013.
APA	Zhou, Yin-Ning,Luo, Zheng-Hong,Chen, Jian-Hua,&罗正鸿.(2013).Theoretical modeling coupled with experimental study on the preparation and characterization comparison of fluorinated copolymers: Effect of chain structure on copolymer properties.http://dx.doi.org/10.1002/aic.14057.
MLA	Zhou, Yin-Ning,et al."Theoretical modeling coupled with experimental study on the preparation and characterization comparison of fluorinated copolymers: Effect of chain structure on copolymer properties".http://dx.doi.org/10.1002/aic.14057 (2013).