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Fabrication of Au/Pd alloy nanoparticle/Pichia pastoris composites: a microorganism-mediated approach
Chen, Huimei ; Sun, Daohua ; Jiang, Xinde ; Jing, Xiaolian ; Lu, Fenfen ; Odoom-Wubah, Tareque ; Zheng, Yanmei ; Huang, Jiale ; Li, Qingbiao ; Sun DH(孙道华) ; Jing XL(景孝廉) ; Zheng YM(郑艳梅) ; Huang JL(黄加乐) ; Li QB(李清彪)
刊名http://dx.doi.org/10.1039/c3ra41215f
2013
关键词GOLD NANOPARTICLES BIMETALLIC NANOPARTICLES METAL NANOPARTICLES EXTRACELLULAR BIOSYNTHESIS PALLADIUM NANOPARTICLES SILVER NANOPARTICLES HYDROGENATION REDUCTION CATALYSTS NANOMATERIALS
英文摘要Fundamental Research Funds for Central Universities [2010121051]; NSFC projects [21106117, 21036004]; Synthesis of metal nanoparticles (NPs) is in the limelight in modern nanotechnology. In this present study, bimetallic Au/Pd NP/Pichia pastoris composites were successfully fabricated through a one-pot microbial reduction of aqueous HAuCl4 and PdCl2 in the presence of H-2 as an electron donor. Interestingly, flower-like alloy Au/Pd NP/Pichia pastoris composites were obtained under the following conditions, NaCl concentration 0.9% (w/v), molar ratio of Au/Pd (1 : 2) and the time for pre-adsorption of Au(III) and Pd(II) ions 15 min, through fresh yeast reduction. The mapping results from scanning transmission electron microscopy (STEM) with a high-angle annular dark field detector confirmed that the Au/Pd NPs on the surface of the yeast were indeed alloy. Furthermore, the energy dispersive X-ray (EDX) and X-ray photoelectron spectroscopy (XPS) measurements showed that the composition of the bimetallic NPs were consistent with the initial molar ratio of the precursors.
语种英语
出版者ROYAL SOC CHEMISTRY
内容类型期刊论文
源URL[http://dspace.xmu.edu.cn/handle/2288/88741]  
专题化学化工-已发表论文
推荐引用方式
GB/T 7714
Chen, Huimei,Sun, Daohua,Jiang, Xinde,et al. Fabrication of Au/Pd alloy nanoparticle/Pichia pastoris composites: a microorganism-mediated approach[J]. http://dx.doi.org/10.1039/c3ra41215f,2013.
APA Chen, Huimei.,Sun, Daohua.,Jiang, Xinde.,Jing, Xiaolian.,Lu, Fenfen.,...&李清彪.(2013).Fabrication of Au/Pd alloy nanoparticle/Pichia pastoris composites: a microorganism-mediated approach.http://dx.doi.org/10.1039/c3ra41215f.
MLA Chen, Huimei,et al."Fabrication of Au/Pd alloy nanoparticle/Pichia pastoris composites: a microorganism-mediated approach".http://dx.doi.org/10.1039/c3ra41215f (2013).
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