Step-by-step assembly of 4d-4f-3d complex based on heptamolybdate anion

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	Step-by-step assembly of 4d-4f-3d complex based on heptamolybdate anion
	Wu, Shuting ; Deng, Binbin ; Jiang, Xiuling ; Li, Ronghua ; Guo, Jiangbin ; Lai, Fulong ; Huang, Xihe ; Huang, Changcang ; Guo JB(郭江彬)
刊名	http://dx.doi.org/10.1016/j.jssc.2012.06.049
	2012-12
关键词	CRYSTAL-STRUCTURE MAGNETIC-PROPERTIES KEGGIN-TYPE LUMINESCENCE PROPERTIES TRANSITION OXIDATION FRAMEWORK TOPOLOGY CLUSTERS
英文摘要	National Natural Science Foundation of China [21001026, 61008040]; Innovation Fund for Young Scientist of Fujian Province [2010J05022]; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences [20110006]; Fuzhou University [2009-XY-5]; Four new complexes, (NH4)(11.9)[Ln(4.7)(MoO4)(H2O)(23)(Mo7O24)(4)]center dot xH(2)O (Ln=Pr, x=34 (1); Ln=-Nd, x=19 (2)), [NH4](28)[Ce-8(MoO4)(2)(H2O)(31)(Mo7O24)(8)]center dot 74H(2)O (3) (NH4)(26)[CoPr8(MoO4)(2)(H2O)(33)(Mo7O24)(8)]center dot 54H(2)O. (4) have been synthesized and characterized by single-crystal and powder X-ray diffraction, CHN elemental analyses TGA analyses, IR and UV-Vis spectroscopy. Complex 1-3 are OD compounds constructed by the connection between Ln(III) ions and [Mo7O24](6-) unit. In complex 4. the existence of Coll connects the polyanion clusters into 1D chain. The introduction of 3d metal (cobalt cation) and 4f metal (Ln=Nd-III, Ce-III) encourages the coordination capability for [Mo7O24](6-) unit, which shows interesting coordination modes. The [Mo7O24](6-) unit in 1-4 shows three new coordination modes, connecting up to four metal cations. Complexes 1-4 show antiferromagnetic behavior via variable temperature magnetic study. The photoluminescence spectrum indicates the photoluminescence property for 4. (C) 2012 Elsevier Inc. All rights reserved.
语种	英语
出版者	J SOLID STATE CHEM
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/88357]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Wu, Shuting,Deng, Binbin,Jiang, Xiuling,et al. Step-by-step assembly of 4d-4f-3d complex based on heptamolybdate anion[J]. http://dx.doi.org/10.1016/j.jssc.2012.06.049,2012.
APA	Wu, Shuting.,Deng, Binbin.,Jiang, Xiuling.,Li, Ronghua.,Guo, Jiangbin.,...&郭江彬.(2012).Step-by-step assembly of 4d-4f-3d complex based on heptamolybdate anion.http://dx.doi.org/10.1016/j.jssc.2012.06.049.
MLA	Wu, Shuting,et al."Step-by-step assembly of 4d-4f-3d complex based on heptamolybdate anion".http://dx.doi.org/10.1016/j.jssc.2012.06.049 (2012).