A unique open inorganic-organic framework with alternate hexa- and penta-coordinate cobalt(II) sites Synthesis, crystal structure and magnetic properties of Co-3(C4H4O4)(25)(OH) (n)center dot 05nH(2)O

CORC > 厦门大学 > 化学化工－已发表论文

	A unique open inorganic-organic framework with alternate hexa- and penta-coordinate cobalt(II) sites Synthesis, crystal structure and magnetic properties of Co-3(C4H4O4)(25)(OH) (n)center dot 05nH(2)O
	Long, L. S. ; Chen, X. M. ; Tong, M. L. ; Sun, Z. G. ; Ren, Y. P. ; Huang, R. B. ; Zheng, L. S. ; Zheng LS(郑兰荪)
刊名	http://dx.doi.org/10.1039/b105482c
	2001-10-07
关键词	COUPLED OXIDATION CARBOXYLATE CHANNELS DESIGN OCTAETHYLPORPHYRIN CHEMISTRY COMPLEXES
英文摘要	A three-dimensional open-framework with unprecedented alternate hexa- and penta-coordinate cobalt(a) sites was obtained from the hydrothermal reaction of cobalt nitrate and succinate in a basic solution. Of the four crystallographically independent Co(a) atoms in the crystal structure of this compound, three are hexa-coordinated and one penta-coordinated. The cobalt(II) atoms are linked by edge-sharing CoOn (n = 5 or 6) polyhedrons. The temperature dependence of the magnetic susceptibility of this compound shows strong antiferromagnetic interaction between the metal atoms.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/63795]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Long, L. S.,Chen, X. M.,Tong, M. L.,et al. A unique open inorganic-organic framework with alternate hexa- and penta-coordinate cobalt(II) sites Synthesis, crystal structure and magnetic properties of Co-3(C4H4O4)(25)(OH) (n)center dot 05nH(2)O[J]. http://dx.doi.org/10.1039/b105482c,2001.
APA	Long, L. S..,Chen, X. M..,Tong, M. L..,Sun, Z. G..,Ren, Y. P..,...&郑兰荪.(2001).A unique open inorganic-organic framework with alternate hexa- and penta-coordinate cobalt(II) sites Synthesis, crystal structure and magnetic properties of Co-3(C4H4O4)(25)(OH) (n)center dot 05nH(2)O.http://dx.doi.org/10.1039/b105482c.
MLA	Long, L. S.,et al."A unique open inorganic-organic framework with alternate hexa- and penta-coordinate cobalt(II) sites Synthesis, crystal structure and magnetic properties of Co-3(C4H4O4)(25)(OH) (n)center dot 05nH(2)O".http://dx.doi.org/10.1039/b105482c (2001).